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Entropy directs the self-assembly of supramolecular palladium coordination macrocycles and cages

The self-assembly of palladium-based cages is frequently rationalized via the cumulative enthalpy (ΔH) of bonds between coordination nodes (M, i.e., Pd) and ligand (L) components. This focus on enthalpic rationale limits the complete understanding of the Gibbs free energy (ΔG) for self-assembly, as...

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Detalles Bibliográficos
Autores principales: Poole III, D. A., Bobylev, E. O., Mathew, S., Reek, J. N. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9430592/
https://www.ncbi.nlm.nih.gov/pubmed/36128226
http://dx.doi.org/10.1039/d2sc03154j

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