Cargando…

Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-di­hydro-1H-spiro­[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbo­nitrile dimethyl sulfoxide disolvate

In the title compound, C(16)H(11)BrN(6)O·2C(2)H(6)OS, the 1,2,3,7-tetra­hydro­imid­azo[1,2-a]pyridine ring system and the oxindole moiety are both nearly planar [maximum deviations = 0.042 (2) and 0.115 (2) Å, respectively] and their planes form a dihedral angle of 86.04 (5)° with each other. Inter­...

Descripción completa

Detalles Bibliográficos
Autores principales: Naghiyev, Farid N., Khrustalev, Victor N., Novikov, Anton P., Akkurt, Mehmet, Rzayev, Rovnag M., Akobirshoeva, Anzurat A., Mamedov, Ibrahim G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431780/
https://www.ncbi.nlm.nih.gov/pubmed/36072149
http://dx.doi.org/10.1107/S2056989022004741
Descripción
Sumario:In the title compound, C(16)H(11)BrN(6)O·2C(2)H(6)OS, the 1,2,3,7-tetra­hydro­imid­azo[1,2-a]pyridine ring system and the oxindole moiety are both nearly planar [maximum deviations = 0.042 (2) and 0.115 (2) Å, respectively] and their planes form a dihedral angle of 86.04 (5)° with each other. Inter­molecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds link mol­ecules in the crystal through the O atoms of the solvent mol­ecules, generating a three-dimensional network. A Hirshfeld surface analysis was performed to further analyse the inter­molecular inter­actions.