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Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate
In the title compound, C(16)H(11)BrN(6)O·2C(2)H(6)OS, the 1,2,3,7-tetrahydroimidazo[1,2-a]pyridine ring system and the oxindole moiety are both nearly planar [maximum deviations = 0.042 (2) and 0.115 (2) Å, respectively] and their planes form a dihedral angle of 86.04 (5)° with each other. Inter...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431780/ https://www.ncbi.nlm.nih.gov/pubmed/36072149 http://dx.doi.org/10.1107/S2056989022004741 |
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| author | Naghiyev, Farid N. Khrustalev, Victor N. Novikov, Anton P. Akkurt, Mehmet Rzayev, Rovnag M. Akobirshoeva, Anzurat A. Mamedov, Ibrahim G. |
| author_facet | Naghiyev, Farid N. Khrustalev, Victor N. Novikov, Anton P. Akkurt, Mehmet Rzayev, Rovnag M. Akobirshoeva, Anzurat A. Mamedov, Ibrahim G. |
| author_sort | Naghiyev, Farid N. |
| collection | PubMed |
| description | In the title compound, C(16)H(11)BrN(6)O·2C(2)H(6)OS, the 1,2,3,7-tetrahydroimidazo[1,2-a]pyridine ring system and the oxindole moiety are both nearly planar [maximum deviations = 0.042 (2) and 0.115 (2) Å, respectively] and their planes form a dihedral angle of 86.04 (5)° with each other. Intermolecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds link molecules in the crystal through the O atoms of the solvent molecules, generating a three-dimensional network. A Hirshfeld surface analysis was performed to further analyse the intermolecular interactions. |
| format | Online Article Text |
| id | pubmed-9431780 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-94317802022-09-06 Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate Naghiyev, Farid N. Khrustalev, Victor N. Novikov, Anton P. Akkurt, Mehmet Rzayev, Rovnag M. Akobirshoeva, Anzurat A. Mamedov, Ibrahim G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(16)H(11)BrN(6)O·2C(2)H(6)OS, the 1,2,3,7-tetrahydroimidazo[1,2-a]pyridine ring system and the oxindole moiety are both nearly planar [maximum deviations = 0.042 (2) and 0.115 (2) Å, respectively] and their planes form a dihedral angle of 86.04 (5)° with each other. Intermolecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds link molecules in the crystal through the O atoms of the solvent molecules, generating a three-dimensional network. A Hirshfeld surface analysis was performed to further analyse the intermolecular interactions. International Union of Crystallography 2022-05-10 /pmc/articles/PMC9431780/ /pubmed/36072149 http://dx.doi.org/10.1107/S2056989022004741 Text en © Naghiyev et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Naghiyev, Farid N. Khrustalev, Victor N. Novikov, Anton P. Akkurt, Mehmet Rzayev, Rovnag M. Akobirshoeva, Anzurat A. Mamedov, Ibrahim G. Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| title | Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| title_full | Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| title_short | Crystal structure and Hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1H-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| title_sort | crystal structure and hirshfeld surface analysis of 5-amino-5′-bromo-2′-oxo-2,3-dihydro-1h-spiro[imidazo[1,2-a]pyridine-7,3′-indoline]-6,8-dicarbonitrile dimethyl sulfoxide disolvate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431780/ https://www.ncbi.nlm.nih.gov/pubmed/36072149 http://dx.doi.org/10.1107/S2056989022004741 |
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