The crystal structure of baeocystin

The title compound, baeocystin or 4-phosphor­yloxy-N-methyl­tryptamine {systematic name: 3-[2-(methylazaniumyl)ethyl]-1H-indol-4-yl hydrogen phosphate}, C(11)H(15)N(2)O(4)P, has a single zwitterionic mol­ecule in the asymmetric unit. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond between t...

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Autores principales: Naeem, Marilyn, Sherwood, Alexander M., Chadeayne, Andrew R., Golen, James A., Manke, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431787/
https://www.ncbi.nlm.nih.gov/pubmed/36072137
http://dx.doi.org/10.1107/S2056989022004467
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author Naeem, Marilyn
Sherwood, Alexander M.
Chadeayne, Andrew R.
Golen, James A.
Manke, David R.
author_facet Naeem, Marilyn
Sherwood, Alexander M.
Chadeayne, Andrew R.
Golen, James A.
Manke, David R.
author_sort Naeem, Marilyn
collection PubMed
description The title compound, baeocystin or 4-phosphor­yloxy-N-methyl­tryptamine {systematic name: 3-[2-(methylazaniumyl)ethyl]-1H-indol-4-yl hydrogen phosphate}, C(11)H(15)N(2)O(4)P, has a single zwitterionic mol­ecule in the asymmetric unit. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond between the ammonium cation and the hydro­phosphate anion. In the crystal, the mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-94317872022-09-06 The crystal structure of baeocystin Naeem, Marilyn Sherwood, Alexander M. Chadeayne, Andrew R. Golen, James A. Manke, David R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, baeocystin or 4-phosphor­yloxy-N-methyl­tryptamine {systematic name: 3-[2-(methylazaniumyl)ethyl]-1H-indol-4-yl hydrogen phosphate}, C(11)H(15)N(2)O(4)P, has a single zwitterionic mol­ecule in the asymmetric unit. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond between the ammonium cation and the hydro­phosphate anion. In the crystal, the mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2022-05-06 /pmc/articles/PMC9431787/ /pubmed/36072137 http://dx.doi.org/10.1107/S2056989022004467 Text en © Naeem et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Naeem, Marilyn
Sherwood, Alexander M.
Chadeayne, Andrew R.
Golen, James A.
Manke, David R.
The crystal structure of baeocystin
title The crystal structure of baeocystin
title_full The crystal structure of baeocystin
title_fullStr The crystal structure of baeocystin
title_full_unstemmed The crystal structure of baeocystin
title_short The crystal structure of baeocystin
title_sort crystal structure of baeocystin
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431787/
https://www.ncbi.nlm.nih.gov/pubmed/36072137
http://dx.doi.org/10.1107/S2056989022004467
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