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Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
In the title compound, C(23)H(16)N(6)O(3), the central five-membered cyclopentene ring adopts an envelope conformation while the five-membered spiro 2,3-dihydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-dihydro-2H-indol-2-one units is in an axial positio...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431790/ https://www.ncbi.nlm.nih.gov/pubmed/36072153 http://dx.doi.org/10.1107/S2056989022005370 |
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author | Naghiyev, Farid N. Khrustalev, Victor N. Fortalnova, Elena A. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. |
author_facet | Naghiyev, Farid N. Khrustalev, Victor N. Fortalnova, Elena A. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. |
author_sort | Naghiyev, Farid N. |
collection | PubMed |
description | In the title compound, C(23)H(16)N(6)O(3), the central five-membered cyclopentene ring adopts an envelope conformation while the five-membered spiro 2,3-dihydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-dihydro-2H-indol-2-one units is in an axial position and the other is in a bisectional position. The methyl methanimidate unit is in an equatorial position. The crystal structure of the title compound is consolidated by intermolecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds, forming a three dimensional network. |
format | Online Article Text |
id | pubmed-9431790 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94317902022-09-06 Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent Naghiyev, Farid N. Khrustalev, Victor N. Fortalnova, Elena A. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(23)H(16)N(6)O(3), the central five-membered cyclopentene ring adopts an envelope conformation while the five-membered spiro 2,3-dihydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-dihydro-2H-indol-2-one units is in an axial position and the other is in a bisectional position. The methyl methanimidate unit is in an equatorial position. The crystal structure of the title compound is consolidated by intermolecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds, forming a three dimensional network. International Union of Crystallography 2022-05-24 /pmc/articles/PMC9431790/ /pubmed/36072153 http://dx.doi.org/10.1107/S2056989022005370 Text en © Naghiyev et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Naghiyev, Farid N. Khrustalev, Victor N. Fortalnova, Elena A. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
title | Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
title_full | Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
title_fullStr | Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
title_short | Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
title_sort | crystal structure and hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431790/ https://www.ncbi.nlm.nih.gov/pubmed/36072153 http://dx.doi.org/10.1107/S2056989022005370 |
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