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Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent

In the title compound, C(23)H(16)N(6)O(3), the central five-membered cyclo­pentene ring adopts an envelope conformation while the five-membered spiro 2,3-di­hydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-di­hydro-2H-indol-2-one units is in an axial positio...

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Autores principales: Naghiyev, Farid N., Khrustalev, Victor N., Fortalnova, Elena A., Akkurt, Mehmet, Khalilov, Ali N., Bhattarai, Ajaya, Mamedov, İbrahim G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431790/
https://www.ncbi.nlm.nih.gov/pubmed/36072153
http://dx.doi.org/10.1107/S2056989022005370
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author Naghiyev, Farid N.
Khrustalev, Victor N.
Fortalnova, Elena A.
Akkurt, Mehmet
Khalilov, Ali N.
Bhattarai, Ajaya
Mamedov, İbrahim G.
author_facet Naghiyev, Farid N.
Khrustalev, Victor N.
Fortalnova, Elena A.
Akkurt, Mehmet
Khalilov, Ali N.
Bhattarai, Ajaya
Mamedov, İbrahim G.
author_sort Naghiyev, Farid N.
collection PubMed
description In the title compound, C(23)H(16)N(6)O(3), the central five-membered cyclo­pentene ring adopts an envelope conformation while the five-membered spiro 2,3-di­hydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-di­hydro-2H-indol-2-one units is in an axial position and the other is in a bis­ectional position. The methyl methanimidate unit is in an equatorial position. The crystal structure of the title compound is consolidated by inter­molecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds, forming a three dimensional network.
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spelling pubmed-94317902022-09-06 Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent Naghiyev, Farid N. Khrustalev, Victor N. Fortalnova, Elena A. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(23)H(16)N(6)O(3), the central five-membered cyclo­pentene ring adopts an envelope conformation while the five-membered spiro 2,3-di­hydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-di­hydro-2H-indol-2-one units is in an axial position and the other is in a bis­ectional position. The methyl methanimidate unit is in an equatorial position. The crystal structure of the title compound is consolidated by inter­molecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds, forming a three dimensional network. International Union of Crystallography 2022-05-24 /pmc/articles/PMC9431790/ /pubmed/36072153 http://dx.doi.org/10.1107/S2056989022005370 Text en © Naghiyev et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Naghiyev, Farid N.
Khrustalev, Victor N.
Fortalnova, Elena A.
Akkurt, Mehmet
Khalilov, Ali N.
Bhattarai, Ajaya
Mamedov, İbrahim G.
Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
title Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
title_full Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
title_fullStr Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
title_short Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
title_sort crystal structure and hirshfeld surface analysis of methyl 4′-amino-3′,5′-di­cyano-2,2′′-dioxodi­spiro[indoline-3,1′-cyclo­pentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431790/
https://www.ncbi.nlm.nih.gov/pubmed/36072153
http://dx.doi.org/10.1107/S2056989022005370
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