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Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction

A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of...

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Detalles Bibliográficos
Autores principales: Lehmann, Paul, Jopp, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9437442/
https://www.ncbi.nlm.nih.gov/pubmed/35920571
http://dx.doi.org/10.1002/open.202200135
Descripción
Sumario:A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of n‐butanol. A direct correlation between the availability of hydroxy groups and the overall activity as well as an enhanced recyclability of the biocatalyst has been found for the glucose‐based ionic liquids.