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Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9437442/ https://www.ncbi.nlm.nih.gov/pubmed/35920571 http://dx.doi.org/10.1002/open.202200135 |
Sumario: | A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of n‐butanol. A direct correlation between the availability of hydroxy groups and the overall activity as well as an enhanced recyclability of the biocatalyst has been found for the glucose‐based ionic liquids. |
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