Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction

A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of...

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Detalles Bibliográficos
Autores principales: Lehmann, Paul, Jopp, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9437442/
https://www.ncbi.nlm.nih.gov/pubmed/35920571
http://dx.doi.org/10.1002/open.202200135
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author Lehmann, Paul
Jopp, Stefan
author_facet Lehmann, Paul
Jopp, Stefan
author_sort Lehmann, Paul
collection PubMed
description A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of n‐butanol. A direct correlation between the availability of hydroxy groups and the overall activity as well as an enhanced recyclability of the biocatalyst has been found for the glucose‐based ionic liquids.
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spelling pubmed-94374422022-09-09 Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction Lehmann, Paul Jopp, Stefan ChemistryOpen Research Articles A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three‐step reaction procedures. These carbohydrate‐based ionic liquids were studied and compared to commercially available imidazolium‐based ionic liquids as supports for Novozym 435 in the acrylation of n‐butanol. A direct correlation between the availability of hydroxy groups and the overall activity as well as an enhanced recyclability of the biocatalyst has been found for the glucose‐based ionic liquids. John Wiley and Sons Inc. 2022-08-03 /pmc/articles/PMC9437442/ /pubmed/35920571 http://dx.doi.org/10.1002/open.202200135 Text en © 2022 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Research Articles
Lehmann, Paul
Jopp, Stefan
Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
title Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
title_full Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
title_fullStr Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
title_full_unstemmed Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
title_short Novel Glucosylimidazolium Ionic‐Liquid‐Supported Novozym 435 Catalysts – A Proof of Concept for an Acrylation Reaction
title_sort novel glucosylimidazolium ionic‐liquid‐supported novozym 435 catalysts – a proof of concept for an acrylation reaction
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9437442/
https://www.ncbi.nlm.nih.gov/pubmed/35920571
http://dx.doi.org/10.1002/open.202200135
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AT joppstefan novelglucosylimidazoliumionicliquidsupportednovozym435catalystsaproofofconceptforanacrylationreaction

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