Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts

Ruthenium (Ru) is the one of the most promising catalysts for polyolefin hydrogenolysis. Its performance varies widely with the support, but the reasons remain unknown. Here, we introduce a simple synthetic strategy (using ammonia as a modulator) to tune metal-support interactions and apply it to Ru...

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Detalles Bibliográficos
Autores principales: Kots, Pavel A., Xie, Tianjun, Vance, Brandon C., Quinn, Caitlin M., de Mello, Matheus Dorneles, Boscoboinik, J. Anibal, Wang, Cong, Kumar, Pawan, Stach, Eric A., Marinkovic, Nebojsa S., Ma, Lu, Ehrlich, Steven N., Vlachos, Dionisios G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9440920/
https://www.ncbi.nlm.nih.gov/pubmed/36057603
http://dx.doi.org/10.1038/s41467-022-32934-5

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