Switching between Hydrogenation and Olefin Transposition Catalysis via Silencing NH Cooperativity in Mn(I) Pincer Complexes

[Image: see text] While Mn-catalyzed (de)hydrogenation of carbonyl derivatives has been well established, the reactivity of Mn hydrides with olefins remains very rare. Herein, we report a Mn(I) pincer complex that effectively promotes site-controlled transposition of olefins. This reactivity is show...

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Detalles Bibliográficos
Autores principales: Yang, Wenjun, Chernyshov, Ivan Yu., Weber, Manuela, Pidko, Evgeny A., Filonenko, Georgy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442580/
https://www.ncbi.nlm.nih.gov/pubmed/36082051
http://dx.doi.org/10.1021/acscatal.2c02963

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442580/
https://www.ncbi.nlm.nih.gov/pubmed/36082051
http://dx.doi.org/10.1021/acscatal.2c02963

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