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AuCl(3)-Catalyzed Hemiacetal Activation for the Stereoselective Synthesis of 2-Deoxy Trehalose Derivatives

[Image: see text] A new practical, catalytic, and highly stereoselective method for directly accessing 1,1-α,α′-linked 2-deoxy trehalose analogues via AuCl(3)-catalyzed dehydrative glycosylation using hemiacetal glycosyl donors and acceptors is described. The method relies on the chemoselective Brøn...

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Detalles Bibliográficos
Autores principales: Jeanneret, Robin, Walz, Carlo, van Meerbeek, Maarten, Coppock, Sarah, Galan, M. Carmen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442795/
https://www.ncbi.nlm.nih.gov/pubmed/35994370
http://dx.doi.org/10.1021/acs.orglett.2c02530

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