Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility

Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).

Detalles Bibliográficos
Autores principales: Mitsudo, Koichi, Inoue, Haruka, Niki, Yuta, Sato, Eisuke, Suga, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443409/
https://www.ncbi.nlm.nih.gov/pubmed/36105727
http://dx.doi.org/10.3762/bjoc.18.107
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author Mitsudo, Koichi
Inoue, Haruka
Niki, Yuta
Sato, Eisuke
Suga, Seiji
author_facet Mitsudo, Koichi
Inoue, Haruka
Niki, Yuta
Sato, Eisuke
Suga, Seiji
author_sort Mitsudo, Koichi
collection PubMed
description Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).
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spelling pubmed-94434092022-09-13 Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility Mitsudo, Koichi Inoue, Haruka Niki, Yuta Sato, Eisuke Suga, Seiji Beilstein J Org Chem Full Research Paper Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C). Beilstein-Institut 2022-08-19 /pmc/articles/PMC9443409/ /pubmed/36105727 http://dx.doi.org/10.3762/bjoc.18.107 Text en Copyright © 2022, Mitsudo et al. https://creativecommons.org/licenses/by/4.0/This is an open access article licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-journals.org/bjoc/terms/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this article could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material.
spellingShingle Full Research Paper
Mitsudo, Koichi
Inoue, Haruka
Niki, Yuta
Sato, Eisuke
Suga, Seiji
Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
title Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
title_full Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
title_fullStr Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
title_full_unstemmed Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
title_short Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
title_sort electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443409/
https://www.ncbi.nlm.nih.gov/pubmed/36105727
http://dx.doi.org/10.3762/bjoc.18.107
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