Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate

The title compound, C(10)H(10)N(4) (2+)·NO(3) (−)·ClO(4) (−), was obtained unexpectedly by the reaction of Co(ClO(4))(2)·6H(2)O and cytidine-5′-monophosphate with 4,4′-azo­pyridine in an aqueous solution of nitric acid. The mol­ecular structure comprises two planar 4,4′-diazenediyldipyridinium dicat...

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Detalles Bibliográficos
Autores principales: Qiu, Qi-Ming, Song, Jian-Biao, Dong, Ai-Guo, Li, Chuan-Tao, Zheng, Zhi-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443795/
https://www.ncbi.nlm.nih.gov/pubmed/36072523
http://dx.doi.org/10.1107/S2056989022007885
Descripción
Sumario:The title compound, C(10)H(10)N(4) (2+)·NO(3) (−)·ClO(4) (−), was obtained unexpectedly by the reaction of Co(ClO(4))(2)·6H(2)O and cytidine-5′-monophosphate with 4,4′-azo­pyridine in an aqueous solution of nitric acid. The mol­ecular structure comprises two planar 4,4′-diazenediyldipyridinium dications lying on inversion centres and perchlorate and nitrate anions in general positions. In the crystal, N—H⋯O hydrogen bonds between dications and anions lead to the formation of [232] chains.

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