Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate

The title compound, C(10)H(10)N(4) (2+)·NO(3) (−)·ClO(4) (−), was obtained unexpectedly by the reaction of Co(ClO(4))(2)·6H(2)O and cytidine-5′-monophosphate with 4,4′-azo­pyridine in an aqueous solution of nitric acid. The mol­ecular structure comprises two planar 4,4′-diazenediyldipyridinium dicat...

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Autores principales: Qiu, Qi-Ming, Song, Jian-Biao, Dong, Ai-Guo, Li, Chuan-Tao, Zheng, Zhi-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443795/
https://www.ncbi.nlm.nih.gov/pubmed/36072523
http://dx.doi.org/10.1107/S2056989022007885
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author Qiu, Qi-Ming
Song, Jian-Biao
Dong, Ai-Guo
Li, Chuan-Tao
Zheng, Zhi-Yuan
author_facet Qiu, Qi-Ming
Song, Jian-Biao
Dong, Ai-Guo
Li, Chuan-Tao
Zheng, Zhi-Yuan
author_sort Qiu, Qi-Ming
collection PubMed
description The title compound, C(10)H(10)N(4) (2+)·NO(3) (−)·ClO(4) (−), was obtained unexpectedly by the reaction of Co(ClO(4))(2)·6H(2)O and cytidine-5′-monophosphate with 4,4′-azo­pyridine in an aqueous solution of nitric acid. The mol­ecular structure comprises two planar 4,4′-diazenediyldipyridinium dications lying on inversion centres and perchlorate and nitrate anions in general positions. In the crystal, N—H⋯O hydrogen bonds between dications and anions lead to the formation of [232] chains.
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spelling pubmed-94437952022-09-06 Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate Qiu, Qi-Ming Song, Jian-Biao Dong, Ai-Guo Li, Chuan-Tao Zheng, Zhi-Yuan Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(10)H(10)N(4) (2+)·NO(3) (−)·ClO(4) (−), was obtained unexpectedly by the reaction of Co(ClO(4))(2)·6H(2)O and cytidine-5′-monophosphate with 4,4′-azo­pyridine in an aqueous solution of nitric acid. The mol­ecular structure comprises two planar 4,4′-diazenediyldipyridinium dications lying on inversion centres and perchlorate and nitrate anions in general positions. In the crystal, N—H⋯O hydrogen bonds between dications and anions lead to the formation of [232] chains. International Union of Crystallography 2022-08-12 /pmc/articles/PMC9443795/ /pubmed/36072523 http://dx.doi.org/10.1107/S2056989022007885 Text en © Qiu et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Qiu, Qi-Ming
Song, Jian-Biao
Dong, Ai-Guo
Li, Chuan-Tao
Zheng, Zhi-Yuan
Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
title Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
title_full Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
title_fullStr Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
title_full_unstemmed Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
title_short Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
title_sort crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443795/
https://www.ncbi.nlm.nih.gov/pubmed/36072523
http://dx.doi.org/10.1107/S2056989022007885
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