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Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine

The title compound, C(24)H(19)NO, was obtained via the reaction of (1E,2E)-3-(3-meth­oxy­phen­yl)-1-phenyl­prop-2-en-1-one with ethyl 2-oxo­propano­ate, using NH(4)I as a catalyst. The compound crystallizes in the monoclinic space group I2/a. In the mol­ecule, the four rings are not in the same plan...

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Autores principales: Cheng, Dong, Meng, Xiang-Zhen, Tian, Fuyu, Yan, Dong, Wang, Xiaofei, Qian, Xueli, Wang, Junnan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443808/
https://www.ncbi.nlm.nih.gov/pubmed/36072513
http://dx.doi.org/10.1107/S2056989022007812
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author Cheng, Dong
Meng, Xiang-Zhen
Tian, Fuyu
Yan, Dong
Wang, Xiaofei
Qian, Xueli
Wang, Junnan
author_facet Cheng, Dong
Meng, Xiang-Zhen
Tian, Fuyu
Yan, Dong
Wang, Xiaofei
Qian, Xueli
Wang, Junnan
author_sort Cheng, Dong
collection PubMed
description The title compound, C(24)H(19)NO, was obtained via the reaction of (1E,2E)-3-(3-meth­oxy­phen­yl)-1-phenyl­prop-2-en-1-one with ethyl 2-oxo­propano­ate, using NH(4)I as a catalyst. The compound crystallizes in the monoclinic space group I2/a. In the mol­ecule, the four rings are not in the same plane, the pyridine ring being inclined to the benzene rings by 17.26 (6), 56.16 (3) and 24.50 (6)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions into a three-dimensional network. To further analyse the inter­molecular inter­actions, a Hirshfeld surface analysis was performed. Hirshfeld surface analysis indicates that the most abundant contributions to the crystal packing are from H⋯H (50.4%), C⋯H/H⋯C (37.9%) and O⋯H/H⋯O (5.1%) inter­actions.
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spelling pubmed-94438082022-09-06 Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine Cheng, Dong Meng, Xiang-Zhen Tian, Fuyu Yan, Dong Wang, Xiaofei Qian, Xueli Wang, Junnan Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(24)H(19)NO, was obtained via the reaction of (1E,2E)-3-(3-meth­oxy­phen­yl)-1-phenyl­prop-2-en-1-one with ethyl 2-oxo­propano­ate, using NH(4)I as a catalyst. The compound crystallizes in the monoclinic space group I2/a. In the mol­ecule, the four rings are not in the same plane, the pyridine ring being inclined to the benzene rings by 17.26 (6), 56.16 (3) and 24.50 (6)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions into a three-dimensional network. To further analyse the inter­molecular inter­actions, a Hirshfeld surface analysis was performed. Hirshfeld surface analysis indicates that the most abundant contributions to the crystal packing are from H⋯H (50.4%), C⋯H/H⋯C (37.9%) and O⋯H/H⋯O (5.1%) inter­actions. International Union of Crystallography 2022-08-23 /pmc/articles/PMC9443808/ /pubmed/36072513 http://dx.doi.org/10.1107/S2056989022007812 Text en © Cheng et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Cheng, Dong
Meng, Xiang-Zhen
Tian, Fuyu
Yan, Dong
Wang, Xiaofei
Qian, Xueli
Wang, Junnan
Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
title Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
title_full Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
title_fullStr Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
title_short Crystal structure and Hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
title_sort crystal structure and hirshfeld surface analysis of 4-(3-meth­oxy­phen­yl)-2,6-di­phenyl­pyridine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9443808/
https://www.ncbi.nlm.nih.gov/pubmed/36072513
http://dx.doi.org/10.1107/S2056989022007812
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