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Colorimetric fluoride detection in dimethyl sulfoxide using a heteroleptic ruthenium(ii) complex with amino and amide groups: X-ray crystallographic and spectroscopic analyses

A bis-heteroleptic ruthenium(ii) complex, [Ru(Hdpa)(2)(H(2)pia)]X(2) (1·X(2); X = Cl, OTf, or F; Hdpa = di-2-pyridylamine; H(2)pia = 2-pycolinamide; OTf(−) = CF(3)SO(3)(−)), was synthesized and spectroscopically and crystallographically characterized. The crystal structures of 1·Cl(2)·2.5H(2)O and 1...

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Detalles Bibliográficos
Autores principales: Toyama, Mari, Hasegawa, Tomoki, Nagao, Noriharu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9450000/
https://www.ncbi.nlm.nih.gov/pubmed/36199333
http://dx.doi.org/10.1039/d2ra03593f

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