Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage

Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates.

Detalles Bibliográficos
Autores principales: Liu, Huijin, Sun, Kai, Li, Xiaolan, Zhang, Jie, Lu, Wei, Luo, Xuzhong, Luo, Haiqing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9450109/
https://www.ncbi.nlm.nih.gov/pubmed/36199296
http://dx.doi.org/10.1039/d2ra04297e
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author Liu, Huijin
Sun, Kai
Li, Xiaolan
Zhang, Jie
Lu, Wei
Luo, Xuzhong
Luo, Haiqing
author_facet Liu, Huijin
Sun, Kai
Li, Xiaolan
Zhang, Jie
Lu, Wei
Luo, Xuzhong
Luo, Haiqing
author_sort Liu, Huijin
collection PubMed
description Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates.
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spelling pubmed-94501092022-10-04 Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage Liu, Huijin Sun, Kai Li, Xiaolan Zhang, Jie Lu, Wei Luo, Xuzhong Luo, Haiqing RSC Adv Chemistry Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates. The Royal Society of Chemistry 2022-09-07 /pmc/articles/PMC9450109/ /pubmed/36199296 http://dx.doi.org/10.1039/d2ra04297e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Liu, Huijin
Sun, Kai
Li, Xiaolan
Zhang, Jie
Lu, Wei
Luo, Xuzhong
Luo, Haiqing
Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
title Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
title_full Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
title_fullStr Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
title_full_unstemmed Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
title_short Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
title_sort palladium-catalyzed phosphorylation of arylsulfonium salts with p(o)h compounds via c–s bond cleavage
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9450109/
https://www.ncbi.nlm.nih.gov/pubmed/36199296
http://dx.doi.org/10.1039/d2ra04297e
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AT sunkai palladiumcatalyzedphosphorylationofarylsulfoniumsaltswithpohcompoundsviacsbondcleavage
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AT zhangjie palladiumcatalyzedphosphorylationofarylsulfoniumsaltswithpohcompoundsviacsbondcleavage
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AT luoxuzhong palladiumcatalyzedphosphorylationofarylsulfoniumsaltswithpohcompoundsviacsbondcleavage
AT luohaiqing palladiumcatalyzedphosphorylationofarylsulfoniumsaltswithpohcompoundsviacsbondcleavage

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