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Review of the application of Cu-containing SSZ-13 in NH(3)-SCR-DeNO(x) and NH(3)-SCO

The reduction of NO(x) emissions has become one of the most important subjects in environmental protection. Cu-containing SSZ-13 is currently the state-of-the-art catalyst for the selective catalytic reduction of NO(x) with ammonia (NH(3)-SCR-DeNO(x)). Although the current-generation catalysts revea...

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Detalles Bibliográficos
Autor principal: Jabłońska, Magdalena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9450943/
https://www.ncbi.nlm.nih.gov/pubmed/36199328
http://dx.doi.org/10.1039/d2ra04301g
Descripción
Sumario:The reduction of NO(x) emissions has become one of the most important subjects in environmental protection. Cu-containing SSZ-13 is currently the state-of-the-art catalyst for the selective catalytic reduction of NO(x) with ammonia (NH(3)-SCR-DeNO(x)). Although the current-generation catalysts reveal enhanced activity and remarkable hydrothermal stability, still open challenges appear. Thus, this review focuses on the progress of Cu-containing SSZ-13 regarding preparation methods, hydrothermal resistance and poisoning as well as reaction mechanisms in NH(3)-SCR-DeNO(x). Remarkably, the paper reviews also the progress of Cu-containing SSZ-13 in the selective ammonia oxidation into nitrogen and water vapor (NH(3)-SCO). The dynamics in the NH(3)-SCR-DeNO(x) and NH(3)-SCO fields make this review timely.