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Aromatic fluorine atom-induced highly amine-sensitive trimethine cyanine dye showing colorimetric and ratiometric fluorescence change

Herein, introducing multiple fluorine atoms into aromatic rings of trimethine cyanine dyes is proposed as a powerful method for dramatically increasing sensitivity to amines. The highly sensitive ratiometric fluorescence properties previously available only by intramolecular addition can be exploite...

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Detalles Bibliográficos
Autores principales: Kani, Ryunosuke, Kubota, Yasuhiro, Inuzuka, Toshiyasu, Funabiki, Kazumasa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9451369/
https://www.ncbi.nlm.nih.gov/pubmed/36199322
http://dx.doi.org/10.1039/d2ra04387d
Descripción
Sumario:Herein, introducing multiple fluorine atoms into aromatic rings of trimethine cyanine dyes is proposed as a powerful method for dramatically increasing sensitivity to amines. The highly sensitive ratiometric fluorescence properties previously available only by intramolecular addition can be exploited in reactions with intermolecular amines or other nucleophiles.