Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)borylbenzenes and o-(Difluorosilyl)borylbenzenes, and Their Fluoride Ion Affinities

[Image: see text] Herein, we report detailed studies on a series of o-(silyl)(boryl)benzenes (1–4), in which the two Lewis acid centers consisting of silicon and boron atoms are linked via an o-phenylene skeleton. o-(Fluorosilyl)(dimesitylboryl)benzenes 1 and 2 were prepared by the reaction of fluor...

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Detalles Bibliográficos
Autores principales: Shimada, Junpei, Tani, Atsushi, Hanazato, Chihiro, Masuyama, Takashi, Yamamoto, Yohsuke, Kawachi, Atsushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9453949/
https://www.ncbi.nlm.nih.gov/pubmed/36092602
http://dx.doi.org/10.1021/acsomega.2c02775

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9453949/
https://www.ncbi.nlm.nih.gov/pubmed/36092602
http://dx.doi.org/10.1021/acsomega.2c02775

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