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Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis

[Image: see text] We report two different approaches to isolate neutral and cationic mesocate-type metallosupramolecular architectures derived from coinage monovalent ions. For this purpose, we use a thiocarbohydrazone ligand, H(2)L (1), conveniently tuned with bulky phosphine groups to stabilize th...

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Detalles Bibliográficos
Autores principales: Fernández-Fariña, Sandra, Martínez-Calvo, Miguel, Maneiro, Marcelino, Seco, José M., Zaragoza, Guillermo, González-Noya, Ana M., Pedrido, Rosa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9455603/
https://www.ncbi.nlm.nih.gov/pubmed/35984909
http://dx.doi.org/10.1021/acs.inorgchem.2c02243