An Environmentally Friendly Inverse Microemulsion Method to Synthesize Polyacrylamide

Polyacrylamide (PAM) was prepared by a new method of inverse microemulsion polymerization, with (NH(4))(2)S(2)O(8)-Na(2)SO(3) as initiator and liquid paraffin/Span80-Op10/AM-H(2)O-NaAc as polymerization system in this paper. The effects of initiator dosage, emulsifier dosage, monomer concentration,...

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Detalles Bibliográficos
Autores principales: Guo, Qing, Yin, Longlong, Wang, Xiao, Yuan, Jing, Zhang, Qianfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9457084/
https://www.ncbi.nlm.nih.gov/pubmed/36079308
http://dx.doi.org/10.3390/ma15175927
Descripción
Sumario:Polyacrylamide (PAM) was prepared by a new method of inverse microemulsion polymerization, with (NH(4))(2)S(2)O(8)-Na(2)SO(3) as initiator and liquid paraffin/Span80-Op10/AM-H(2)O-NaAc as polymerization system in this paper. The effects of initiator dosage, emulsifier dosage, monomer concentration, oil–water ratio, and temperature on molecular weight, electrical conductivity, particle size distribution, and monomer conversion were studied as well. The results indicate that that the more stable Polyacrylamide (PAM) polymer was prepared under the conditions of initiator dosage of 0.4~0.5%, emulsifier dosage of 55~60%, temperature of 40~45 °C, hydrophile–lipophile balance (HLB) value of 8.0~8.2, and NaAc concentration of 3%.

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