Modernized Synthesis Technique of Pr(2)NiO(4+δ)-Based Complex Oxides Using Low-Temperature Salt Melts

Phases based on layered lanthanide nickelates are considered as promising electrode materials for various electrochemical devices, including solid oxide fuel cells and electrolysis cells. While such compounds may be prepared using either solid state or solution-assisted syntheses, each of these approaches entails certain problems. In the present work, we propose a novel approach for the simple and straightforward preparation of Pr(2)NiO(4+δ)-based materials. This approach involves co-melting of initial nitrate components, followed by high-temperature decomposition of the obtained mixture. The developed synthesis method exhibits a number of advantages over conventional techniques, enabling highly dispersed and single-phase powders to be obtained at a reduced synthesis temperature of 1050 °C. Therefore, the results of this work open new possibilities for the cost-effective preparation of Ruddlesden–Popper oxide phases.