Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules

A carbon nanobelt (CNB) is a loop of fused benzene rings and a C(60) molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C(60) molecules in 1,2-dichlorobenzene at room temperature via bottom-up self-a...

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Autores principales: Choi, Sieun, Kurosu, Shunji, Mashiko, Yuta, Minakawa, Takanobu, Maekawa, Toru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9458716/
https://www.ncbi.nlm.nih.gov/pubmed/36076008
http://dx.doi.org/10.1038/s41598-022-19475-z
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author Choi, Sieun
Kurosu, Shunji
Mashiko, Yuta
Minakawa, Takanobu
Maekawa, Toru
author_facet Choi, Sieun
Kurosu, Shunji
Mashiko, Yuta
Minakawa, Takanobu
Maekawa, Toru
author_sort Choi, Sieun
collection PubMed
description A carbon nanobelt (CNB) is a loop of fused benzene rings and a C(60) molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C(60) molecules in 1,2-dichlorobenzene at room temperature via bottom-up self-assembly, setting the molar concentrations of (6,6)CNBs and C(60) molecules at appropriate values, and find that the particles are monodisperse even in water. The present room temperature synthetic methodology may well be applied to the creation of nano/micro structures/materials using basic carbon nano units such as cycloparaphenylene (CPP, carbon nanorings) and fullerenes; e.g., C(60), C(70) and C(59)N.
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spelling pubmed-94587162022-09-10 Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules Choi, Sieun Kurosu, Shunji Mashiko, Yuta Minakawa, Takanobu Maekawa, Toru Sci Rep Article A carbon nanobelt (CNB) is a loop of fused benzene rings and a C(60) molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C(60) molecules in 1,2-dichlorobenzene at room temperature via bottom-up self-assembly, setting the molar concentrations of (6,6)CNBs and C(60) molecules at appropriate values, and find that the particles are monodisperse even in water. The present room temperature synthetic methodology may well be applied to the creation of nano/micro structures/materials using basic carbon nano units such as cycloparaphenylene (CPP, carbon nanorings) and fullerenes; e.g., C(60), C(70) and C(59)N. Nature Publishing Group UK 2022-09-08 /pmc/articles/PMC9458716/ /pubmed/36076008 http://dx.doi.org/10.1038/s41598-022-19475-z Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Choi, Sieun
Kurosu, Shunji
Mashiko, Yuta
Minakawa, Takanobu
Maekawa, Toru
Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules
title Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules
title_full Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules
title_fullStr Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules
title_full_unstemmed Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules
title_short Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C(60) molecules
title_sort room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and c(60) molecules
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9458716/
https://www.ncbi.nlm.nih.gov/pubmed/36076008
http://dx.doi.org/10.1038/s41598-022-19475-z
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