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Unmasking the Iron–Oxo Bond of the [(Ligand)Fe-OIAr](2+/+) Complexes
[Image: see text] ArIO (ArI = 2-((t)BuSO(2))C(6)H(4)I) is an oxidant used to oxidize Fe(II) species to their Fe(IV)-oxo state, enabling hydrogen-atom transfer (HAT) and oxygen-atom transfer (OAT) reactions at low energy barriers. ArIO, as a ligand, generates masked Fe(n)=O species of the type Fe((n-...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9460779/ https://www.ncbi.nlm.nih.gov/pubmed/35920859 http://dx.doi.org/10.1021/jasms.2c00094 |