Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate

In the title compound, C(23)H(19)NO(5), the cyano group adopts an axial orientation and the ester group an equatorial orientation. The dihedral angle between the pendant phenyl group and the benzene ring of the fused-ring system is 25.97 (8)°. Intra­molecular O—H⋯O and C—H⋯O hydrogen bonds are obser...

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Autores principales: Surya Prakash Rao, H., M, Prabakaran, Muthukumaran, Jayaraman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9461999/
https://www.ncbi.nlm.nih.gov/pubmed/36340871
http://dx.doi.org/10.1107/S2414314622001997
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author Surya Prakash Rao, H.
M, Prabakaran
Muthukumaran, Jayaraman
author_facet Surya Prakash Rao, H.
M, Prabakaran
Muthukumaran, Jayaraman
author_sort Surya Prakash Rao, H.
collection PubMed
description In the title compound, C(23)H(19)NO(5), the cyano group adopts an axial orientation and the ester group an equatorial orientation. The dihedral angle between the pendant phenyl group and the benzene ring of the fused-ring system is 25.97 (8)°. Intra­molecular O—H⋯O and C—H⋯O hydrogen bonds are observed and the packing is consolidated by C—H⋯O and C—H⋯π inter­actions. [Image: see text]
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spelling pubmed-94619992022-11-04 Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate Surya Prakash Rao, H. M, Prabakaran Muthukumaran, Jayaraman IUCrdata Data Reports In the title compound, C(23)H(19)NO(5), the cyano group adopts an axial orientation and the ester group an equatorial orientation. The dihedral angle between the pendant phenyl group and the benzene ring of the fused-ring system is 25.97 (8)°. Intra­molecular O—H⋯O and C—H⋯O hydrogen bonds are observed and the packing is consolidated by C—H⋯O and C—H⋯π inter­actions. [Image: see text] International Union of Crystallography 2022-02-25 /pmc/articles/PMC9461999/ /pubmed/36340871 http://dx.doi.org/10.1107/S2414314622001997 Text en © Surya Prakash Rao et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Surya Prakash Rao, H.
M, Prabakaran
Muthukumaran, Jayaraman
Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate
title Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate
title_full Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate
title_fullStr Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate
title_full_unstemmed Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate
title_short Ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6H-benzo[c]chromene-10-carboxyl­ate
title_sort ethyl 10-cyano-7-hy­droxy-6-oxo-3-phenyl-8,9,10,10a-tetra­hydro-6h-benzo[c]chromene-10-carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9461999/
https://www.ncbi.nlm.nih.gov/pubmed/36340871
http://dx.doi.org/10.1107/S2414314622001997
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AT muthukumaranjayaraman ethyl10cyano7hydroxy6oxo3phenyl891010atetrahydro6hbenzocchromene10carboxylate

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