Cargando…
trans-Bis(4-aminopyridine-κN)bis(quinoxaline-2,3-dithiolato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
In the structure of the title solvated complex, [Pt(C(8)H(4)N(2)S(2))(2)(C(5)H(6)N(2))(2)]·C(2)H(6)OS or trans-[Pt(4-ap)(2)(qdt)(2)]·dmso (4-ap = 4-aminopyridyl, C(5)H(6)N(2); qdt = quinoxaline-2,3-dithiolate, C(8)H(4)N(2)S(2); dmso = dimethyl sulfoxide, C(2)H(6)OS) the centrosymmetric complex ex...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462004/ https://www.ncbi.nlm.nih.gov/pubmed/36340877 http://dx.doi.org/10.1107/S2414314622001018 |
Sumario: | In the structure of the title solvated complex, [Pt(C(8)H(4)N(2)S(2))(2)(C(5)H(6)N(2))(2)]·C(2)H(6)OS or trans-[Pt(4-ap)(2)(qdt)(2)]·dmso (4-ap = 4-aminopyridyl, C(5)H(6)N(2); qdt = quinoxaline-2,3-dithiolate, C(8)H(4)N(2)S(2); dmso = dimethyl sulfoxide, C(2)H(6)OS) the centrosymmetric complex exhibits Pt—S distances in agreement with other Pt(IV)—S bond lengths found in platinum(IV) dithiolene complexes. The qdt ligands have intermolecular interactions with an amine hydrogen atom on a 4-ap ligand (hydrogen bonding) and have sandwich π–π interactions with a neighboring qdt ligand. [Image: see text] |
---|