trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate

In the structure of the title solvated complex, [Pt(C(8)H(4)N(2)S(2))(2)(C(5)H(6)N(2))(2)]·C(2)H(6)OS or trans-[Pt(4-ap)(2)(qdt)(2)]·dmso (4-ap = 4-amino­pyridyl, C(5)H(6)N(2); qdt = quinoxaline-2,3-di­thiol­ate, C(8)H(4)N(2)S(2); dmso = dimethyl sulfoxide, C(2)H(6)OS) the centrosymmetric complex ex...

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Autores principales: Hu, Jiandu, Nesterov, Volodymyr V., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462004/
https://www.ncbi.nlm.nih.gov/pubmed/36340877
http://dx.doi.org/10.1107/S2414314622001018
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author Hu, Jiandu
Nesterov, Volodymyr V.
Smucker, Bradley W.
author_facet Hu, Jiandu
Nesterov, Volodymyr V.
Smucker, Bradley W.
author_sort Hu, Jiandu
collection PubMed
description In the structure of the title solvated complex, [Pt(C(8)H(4)N(2)S(2))(2)(C(5)H(6)N(2))(2)]·C(2)H(6)OS or trans-[Pt(4-ap)(2)(qdt)(2)]·dmso (4-ap = 4-amino­pyridyl, C(5)H(6)N(2); qdt = quinoxaline-2,3-di­thiol­ate, C(8)H(4)N(2)S(2); dmso = dimethyl sulfoxide, C(2)H(6)OS) the centrosymmetric complex exhibits Pt—S distances in agreement with other Pt(IV)—S bond lengths found in platinum(IV) di­thiol­ene complexes. The qdt ligands have inter­molecular inter­actions with an amine hydrogen atom on a 4-ap ligand (hydrogen bonding) and have sandwich π–π inter­actions with a neighboring qdt ligand. [Image: see text]
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spelling pubmed-94620042022-11-04 trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate Hu, Jiandu Nesterov, Volodymyr V. Smucker, Bradley W. IUCrdata Data Reports In the structure of the title solvated complex, [Pt(C(8)H(4)N(2)S(2))(2)(C(5)H(6)N(2))(2)]·C(2)H(6)OS or trans-[Pt(4-ap)(2)(qdt)(2)]·dmso (4-ap = 4-amino­pyridyl, C(5)H(6)N(2); qdt = quinoxaline-2,3-di­thiol­ate, C(8)H(4)N(2)S(2); dmso = dimethyl sulfoxide, C(2)H(6)OS) the centrosymmetric complex exhibits Pt—S distances in agreement with other Pt(IV)—S bond lengths found in platinum(IV) di­thiol­ene complexes. The qdt ligands have inter­molecular inter­actions with an amine hydrogen atom on a 4-ap ligand (hydrogen bonding) and have sandwich π–π inter­actions with a neighboring qdt ligand. [Image: see text] International Union of Crystallography 2022-02-03 /pmc/articles/PMC9462004/ /pubmed/36340877 http://dx.doi.org/10.1107/S2414314622001018 Text en © Hu et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hu, Jiandu
Nesterov, Volodymyr V.
Smucker, Bradley W.
trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
title trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
title_full trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
title_fullStr trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
title_full_unstemmed trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
title_short trans-Bis(4-amino­pyridine-κN)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) S,S′)platinum(IV) dimethyl sulfoxide monosolvate
title_sort trans-bis(4-amino­pyridine-κn)bis­(quin­ox­aline-2,3-di­thiol­ato-κ(2) s,s′)platinum(iv) dimethyl sulfoxide monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462004/
https://www.ncbi.nlm.nih.gov/pubmed/36340877
http://dx.doi.org/10.1107/S2414314622001018
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AT smuckerbradleyw transbis4aminopyridineknbisquinoxaline23dithiolatok2ssplatinumivdimethylsulfoxidemonosolvate

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