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Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]

The reaction of AgNO(3) with the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetic acid in the presence of a potassium acetate buffer lead to the formation of a silver(I)–potassium–organic framework, poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[p...

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Detalles Bibliográficos
Autores principales: Pacifico, Jessica, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462006/
https://www.ncbi.nlm.nih.gov/pubmed/36340876
http://dx.doi.org/10.1107/S2414314622000773
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author Pacifico, Jessica
Stoeckli-Evans, Helen
author_facet Pacifico, Jessica
Stoeckli-Evans, Helen
author_sort Pacifico, Jessica
collection PubMed
description The reaction of AgNO(3) with the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetic acid in the presence of a potassium acetate buffer lead to the formation of a silver(I)–potassium–organic framework, poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate], {K(2)[Ag(2)(C(16)H(16)N(2)O(8)S(4))]·5.2H(2)O}( n ), (I). The asymmetric unit is composed of half a binuclear silver complex located about a center of symmetry, a potassium cation and 2.6 disordered water mol­ecules. The whole binuclear silver complex is generated by inversion symmetry with the pyrazine ring being located about an inversion centre. The ligand coordinates in a bis-tetra­dentate manner. The binuclear silver complex anions are linked via bridging Ag⋯S⋯Ag zigzag bonds, forming a network lying parallel to the bc plane. The networks are linked by O(carboxyl­ate)⋯K (+)⋯O(carboxyl­ate) bridging bonds to form a framework. The disordered water mol­ecules are present near to the K(+) cations. [Image: see text]
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spelling pubmed-94620062022-11-04 Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate] Pacifico, Jessica Stoeckli-Evans, Helen IUCrdata Data Reports The reaction of AgNO(3) with the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetic acid in the presence of a potassium acetate buffer lead to the formation of a silver(I)–potassium–organic framework, poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate], {K(2)[Ag(2)(C(16)H(16)N(2)O(8)S(4))]·5.2H(2)O}( n ), (I). The asymmetric unit is composed of half a binuclear silver complex located about a center of symmetry, a potassium cation and 2.6 disordered water mol­ecules. The whole binuclear silver complex is generated by inversion symmetry with the pyrazine ring being located about an inversion centre. The ligand coordinates in a bis-tetra­dentate manner. The binuclear silver complex anions are linked via bridging Ag⋯S⋯Ag zigzag bonds, forming a network lying parallel to the bc plane. The networks are linked by O(carboxyl­ate)⋯K (+)⋯O(carboxyl­ate) bridging bonds to form a framework. The disordered water mol­ecules are present near to the K(+) cations. [Image: see text] International Union of Crystallography 2022-02-01 /pmc/articles/PMC9462006/ /pubmed/36340876 http://dx.doi.org/10.1107/S2414314622000773 Text en © Pacifico and Stoeckli-Evans 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Pacifico, Jessica
Stoeckli-Evans, Helen
Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]
title Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]
title_full Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]
title_fullStr Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]
title_full_unstemmed Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]
title_short Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(I)] 5.2-hydrate]
title_sort poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetato)­disilver(i)] 5.2-hydrate]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462006/
https://www.ncbi.nlm.nih.gov/pubmed/36340876
http://dx.doi.org/10.1107/S2414314622000773
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AT stoecklievanshelen polydipotassiumm62222pyrazine2356tetrayltetrakismethylenetetrakissulfanediyltetraacetatodisilveri52hydrate