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Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate]
The reaction of AgNO(3) with the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetic acid in the presence of a potassium acetate buffer lead to the formation of a silver(I)–potassium–organic framework, poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[p...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462006/ https://www.ncbi.nlm.nih.gov/pubmed/36340876 http://dx.doi.org/10.1107/S2414314622000773 |
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author | Pacifico, Jessica Stoeckli-Evans, Helen |
author_facet | Pacifico, Jessica Stoeckli-Evans, Helen |
author_sort | Pacifico, Jessica |
collection | PubMed |
description | The reaction of AgNO(3) with the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetic acid in the presence of a potassium acetate buffer lead to the formation of a silver(I)–potassium–organic framework, poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate], {K(2)[Ag(2)(C(16)H(16)N(2)O(8)S(4))]·5.2H(2)O}( n ), (I). The asymmetric unit is composed of half a binuclear silver complex located about a center of symmetry, a potassium cation and 2.6 disordered water molecules. The whole binuclear silver complex is generated by inversion symmetry with the pyrazine ring being located about an inversion centre. The ligand coordinates in a bis-tetradentate manner. The binuclear silver complex anions are linked via bridging Ag⋯S⋯Ag zigzag bonds, forming a network lying parallel to the bc plane. The networks are linked by O(carboxylate)⋯K (+)⋯O(carboxylate) bridging bonds to form a framework. The disordered water molecules are present near to the K(+) cations. [Image: see text] |
format | Online Article Text |
id | pubmed-9462006 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94620062022-11-04 Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] Pacifico, Jessica Stoeckli-Evans, Helen IUCrdata Data Reports The reaction of AgNO(3) with the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetic acid in the presence of a potassium acetate buffer lead to the formation of a silver(I)–potassium–organic framework, poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate], {K(2)[Ag(2)(C(16)H(16)N(2)O(8)S(4))]·5.2H(2)O}( n ), (I). The asymmetric unit is composed of half a binuclear silver complex located about a center of symmetry, a potassium cation and 2.6 disordered water molecules. The whole binuclear silver complex is generated by inversion symmetry with the pyrazine ring being located about an inversion centre. The ligand coordinates in a bis-tetradentate manner. The binuclear silver complex anions are linked via bridging Ag⋯S⋯Ag zigzag bonds, forming a network lying parallel to the bc plane. The networks are linked by O(carboxylate)⋯K (+)⋯O(carboxylate) bridging bonds to form a framework. The disordered water molecules are present near to the K(+) cations. [Image: see text] International Union of Crystallography 2022-02-01 /pmc/articles/PMC9462006/ /pubmed/36340876 http://dx.doi.org/10.1107/S2414314622000773 Text en © Pacifico and Stoeckli-Evans 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Pacifico, Jessica Stoeckli-Evans, Helen Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] |
title | Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] |
title_full | Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] |
title_fullStr | Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] |
title_full_unstemmed | Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] |
title_short | Poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(I)] 5.2-hydrate] |
title_sort | poly[dipotassium [(μ(6)-2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetrayltetrakis(methylene)]tetrakis(sulfanediyl)}tetraacetato)disilver(i)] 5.2-hydrate] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462006/ https://www.ncbi.nlm.nih.gov/pubmed/36340876 http://dx.doi.org/10.1107/S2414314622000773 |
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