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1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate

The title solvated molecular salt, [MeGluVIm]I (MeGluVIm = 1-(methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium), or C(12)H(19)N(2)O(5) (+)·I(−)·C(3)H(7)NO, was synthesized from methyl-α-d-6-iodo­gluco­pyran­oside and vinyl­imidazole in DMF. It crystallizes through precipitation from ethyl aceta...

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Detalles Bibliográficos
Autores principales: Lambrecht, Sina, Villinger, Alexander, Jopp, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462008/
https://www.ncbi.nlm.nih.gov/pubmed/36339811
http://dx.doi.org/10.1107/S2414314622002656
Descripción
Sumario:The title solvated molecular salt, [MeGluVIm]I (MeGluVIm = 1-(methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium), or C(12)H(19)N(2)O(5) (+)·I(−)·C(3)H(7)NO, was synthesized from methyl-α-d-6-iodo­gluco­pyran­oside and vinyl­imidazole in DMF. It crystallizes through precipitation from ethyl acetate solution directly after the reaction procedure. The crystal structure consists of an iodide anion and a [MeGluVIm] cation. Furthermore, the crystal structure contains one mol­ecule of DMF, which accepts two O—H⋯H hydrogen bonds from the OH groups of the gluco­pyran­oside. [Image: see text]