1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate

The title solvated molecular salt, [MeGluVIm]I (MeGluVIm = 1-(methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium), or C(12)H(19)N(2)O(5) (+)·I(−)·C(3)H(7)NO, was synthesized from methyl-α-d-6-iodo­gluco­pyran­oside and vinyl­imidazole in DMF. It crystallizes through precipitation from ethyl aceta...

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Detalles Bibliográficos
Autores principales: Lambrecht, Sina, Villinger, Alexander, Jopp, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462008/
https://www.ncbi.nlm.nih.gov/pubmed/36339811
http://dx.doi.org/10.1107/S2414314622002656
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author Lambrecht, Sina
Villinger, Alexander
Jopp, Stefan
author_facet Lambrecht, Sina
Villinger, Alexander
Jopp, Stefan
author_sort Lambrecht, Sina
collection PubMed
description The title solvated molecular salt, [MeGluVIm]I (MeGluVIm = 1-(methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium), or C(12)H(19)N(2)O(5) (+)·I(−)·C(3)H(7)NO, was synthesized from methyl-α-d-6-iodo­gluco­pyran­oside and vinyl­imidazole in DMF. It crystallizes through precipitation from ethyl acetate solution directly after the reaction procedure. The crystal structure consists of an iodide anion and a [MeGluVIm] cation. Furthermore, the crystal structure contains one mol­ecule of DMF, which accepts two O—H⋯H hydrogen bonds from the OH groups of the gluco­pyran­oside. [Image: see text]
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spelling pubmed-94620082022-11-04 1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate Lambrecht, Sina Villinger, Alexander Jopp, Stefan IUCrdata Data Reports The title solvated molecular salt, [MeGluVIm]I (MeGluVIm = 1-(methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium), or C(12)H(19)N(2)O(5) (+)·I(−)·C(3)H(7)NO, was synthesized from methyl-α-d-6-iodo­gluco­pyran­oside and vinyl­imidazole in DMF. It crystallizes through precipitation from ethyl acetate solution directly after the reaction procedure. The crystal structure consists of an iodide anion and a [MeGluVIm] cation. Furthermore, the crystal structure contains one mol­ecule of DMF, which accepts two O—H⋯H hydrogen bonds from the OH groups of the gluco­pyran­oside. [Image: see text] International Union of Crystallography 2022-03-10 /pmc/articles/PMC9462008/ /pubmed/36339811 http://dx.doi.org/10.1107/S2414314622002656 Text en © Lambrecht et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lambrecht, Sina
Villinger, Alexander
Jopp, Stefan
1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
title 1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
title_full 1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
title_fullStr 1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
title_full_unstemmed 1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
title_short 1-(Methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
title_sort 1-(methyl-α-d-gluco­pyran­osid-6-yl)-3-vinyl­imidazolium iodide di­methyl­formamide monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462008/
https://www.ncbi.nlm.nih.gov/pubmed/36339811
http://dx.doi.org/10.1107/S2414314622002656
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AT joppstefan 1methyladglucopyranosid6yl3vinylimidazoliumiodidedimethylformamidemonosolvate

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