Tetra-μ-acetato-κ(8) O:O′-bis­[(3-chloro­pyridine-κN)ruthenium(II,III)](Ru—Ru) hexa­fluorido­phosphate 1,2-di­chloro­ethane monosolvate

The title compound, [Ru(2)(μ-O(2)CCH(3))(4)(C(5)H(4)ClN)(2)]PF(6)·C(2)H(4)Cl(2), was obtained via a rapid substitution reaction of 3-chloro­pyridine for water in [Ru(2)(μ-O(2)CCH(3))(4)(H(2)O)(2)]PF(6) in 2-propanol and subsequent crystallization from a di­chloro­ethane solution. The cationic diruth...

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Detalles Bibliográficos
Autores principales: Aquino, Anthony J., Gerrior, Daniel, Cameron, T. Stanley, Robertson, Katherine N., Aquino, Manuel A.S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462009/
https://www.ncbi.nlm.nih.gov/pubmed/36339799
http://dx.doi.org/10.1107/S2414314622002498
Descripción
Sumario:The title compound, [Ru(2)(μ-O(2)CCH(3))(4)(C(5)H(4)ClN)(2)]PF(6)·C(2)H(4)Cl(2), was obtained via a rapid substitution reaction of 3-chloro­pyridine for water in [Ru(2)(μ-O(2)CCH(3))(4)(H(2)O)(2)]PF(6) in 2-propanol and subsequent crystallization from a di­chloro­ethane solution. The cationic diruthenium(II,III) tetra­acetate core lies on a crystallographic inversion center with Ru—Ru and Ru—N bond lengths of 2.2738 (3) and 2.2920 (17) Å, respectively. The Ru—Ru—N bond angle is close to linear at 176.48 (4)°, and a significant π-stacking inter­action of 3.5649 (16) Å is seen between overlapping pyridine rings of adjacent cations. [Image: see text]

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