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Tetra-μ-acetato-κ(8) O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate
The title compound, [Ru(2)(μ-O(2)CCH(3))(4)(C(5)H(4)ClN)(2)]PF(6)·C(2)H(4)Cl(2), was obtained via a rapid substitution reaction of 3-chloropyridine for water in [Ru(2)(μ-O(2)CCH(3))(4)(H(2)O)(2)]PF(6) in 2-propanol and subsequent crystallization from a dichloroethane solution. The cationic diruth...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462009/ https://www.ncbi.nlm.nih.gov/pubmed/36339799 http://dx.doi.org/10.1107/S2414314622002498 |
| _version_ | 1784787081584705536 |
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| author | Aquino, Anthony J. Gerrior, Daniel Cameron, T. Stanley Robertson, Katherine N. Aquino, Manuel A.S. |
| author_facet | Aquino, Anthony J. Gerrior, Daniel Cameron, T. Stanley Robertson, Katherine N. Aquino, Manuel A.S. |
| author_sort | Aquino, Anthony J. |
| collection | PubMed |
| description | The title compound, [Ru(2)(μ-O(2)CCH(3))(4)(C(5)H(4)ClN)(2)]PF(6)·C(2)H(4)Cl(2), was obtained via a rapid substitution reaction of 3-chloropyridine for water in [Ru(2)(μ-O(2)CCH(3))(4)(H(2)O)(2)]PF(6) in 2-propanol and subsequent crystallization from a dichloroethane solution. The cationic diruthenium(II,III) tetraacetate core lies on a crystallographic inversion center with Ru—Ru and Ru—N bond lengths of 2.2738 (3) and 2.2920 (17) Å, respectively. The Ru—Ru—N bond angle is close to linear at 176.48 (4)°, and a significant π-stacking interaction of 3.5649 (16) Å is seen between overlapping pyridine rings of adjacent cations. [Image: see text] |
| format | Online Article Text |
| id | pubmed-9462009 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-94620092022-11-04 Tetra-μ-acetato-κ(8) O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate Aquino, Anthony J. Gerrior, Daniel Cameron, T. Stanley Robertson, Katherine N. Aquino, Manuel A.S. IUCrdata Data Reports The title compound, [Ru(2)(μ-O(2)CCH(3))(4)(C(5)H(4)ClN)(2)]PF(6)·C(2)H(4)Cl(2), was obtained via a rapid substitution reaction of 3-chloropyridine for water in [Ru(2)(μ-O(2)CCH(3))(4)(H(2)O)(2)]PF(6) in 2-propanol and subsequent crystallization from a dichloroethane solution. The cationic diruthenium(II,III) tetraacetate core lies on a crystallographic inversion center with Ru—Ru and Ru—N bond lengths of 2.2738 (3) and 2.2920 (17) Å, respectively. The Ru—Ru—N bond angle is close to linear at 176.48 (4)°, and a significant π-stacking interaction of 3.5649 (16) Å is seen between overlapping pyridine rings of adjacent cations. [Image: see text] International Union of Crystallography 2022-03-10 /pmc/articles/PMC9462009/ /pubmed/36339799 http://dx.doi.org/10.1107/S2414314622002498 Text en © Aquino et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Aquino, Anthony J. Gerrior, Daniel Cameron, T. Stanley Robertson, Katherine N. Aquino, Manuel A.S. Tetra-μ-acetato-κ(8) O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| title | Tetra-μ-acetato-κ(8)
O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| title_full | Tetra-μ-acetato-κ(8)
O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| title_fullStr | Tetra-μ-acetato-κ(8)
O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| title_full_unstemmed | Tetra-μ-acetato-κ(8)
O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| title_short | Tetra-μ-acetato-κ(8)
O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| title_sort | tetra-μ-acetato-κ(8)
o:o′-bis[(3-chloropyridine-κn)ruthenium(ii,iii)](ru—ru) hexafluoridophosphate 1,2-dichloroethane monosolvate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462009/ https://www.ncbi.nlm.nih.gov/pubmed/36339799 http://dx.doi.org/10.1107/S2414314622002498 |
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