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{N′-[(E)-1-(5-Chloro-2-oxidophen­yl)ethyl­idene]-4-meth­oxy­benzohydrazidato-κ(3) O,N′,O′}(1H-imidazole-κN (3))nickel(II)

In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzohydrazide ligand and one N atom from the imidazole mol­ecule. The N(2)O(2) donor...

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Detalles Bibliográficos
Autor principal: Chang, Jian-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462012/
https://www.ncbi.nlm.nih.gov/pubmed/36339807
http://dx.doi.org/10.1107/S2414314622002954
Descripción
Sumario:In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzohydrazide ligand and one N atom from the imidazole mol­ecule. The N(2)O(2) donor set defines an approximate square-planar geometry. The dihedral angles between the imidazole ring and the fused six-membered and meth­oxy­benzene rings are 17.78 (14) and 13.23 (16)°, respectively; the dihedral angle between the C(6) rings is 6.63 (12)°. The most prominent feature of the mol­ecular packing is the formation of 4(1)-helical chains (along the c axis) mediated by imidazole-N—H⋯O(phenoxide) hydrogen bonding; these are linked by methyl-C—H⋯Cl inter­actions. [Image: see text]