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{N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3) O,N′,O′}(1H-imidazole-κN (3))nickel(II)
In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide ligand and one N atom from the imidazole molecule. The N(2)O(2) donor...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462012/ https://www.ncbi.nlm.nih.gov/pubmed/36339807 http://dx.doi.org/10.1107/S2414314622002954 |
Sumario: | In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide ligand and one N atom from the imidazole molecule. The N(2)O(2) donor set defines an approximate square-planar geometry. The dihedral angles between the imidazole ring and the fused six-membered and methoxybenzene rings are 17.78 (14) and 13.23 (16)°, respectively; the dihedral angle between the C(6) rings is 6.63 (12)°. The most prominent feature of the molecular packing is the formation of 4(1)-helical chains (along the c axis) mediated by imidazole-N—H⋯O(phenoxide) hydrogen bonding; these are linked by methyl-C—H⋯Cl interactions. [Image: see text] |
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