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{N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3) O,N′,O′}(1H-imidazole-κN (3))nickel(II)
In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide ligand and one N atom from the imidazole molecule. The N(2)O(2) donor...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462012/ https://www.ncbi.nlm.nih.gov/pubmed/36339807 http://dx.doi.org/10.1107/S2414314622002954 |
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author | Chang, Jian-Guo |
author_facet | Chang, Jian-Guo |
author_sort | Chang, Jian-Guo |
collection | PubMed |
description | In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide ligand and one N atom from the imidazole molecule. The N(2)O(2) donor set defines an approximate square-planar geometry. The dihedral angles between the imidazole ring and the fused six-membered and methoxybenzene rings are 17.78 (14) and 13.23 (16)°, respectively; the dihedral angle between the C(6) rings is 6.63 (12)°. The most prominent feature of the molecular packing is the formation of 4(1)-helical chains (along the c axis) mediated by imidazole-N—H⋯O(phenoxide) hydrogen bonding; these are linked by methyl-C—H⋯Cl interactions. [Image: see text] |
format | Online Article Text |
id | pubmed-9462012 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94620122022-11-04 {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3) O,N′,O′}(1H-imidazole-κN (3))nickel(II) Chang, Jian-Guo IUCrdata Data Reports In the title complex, [Ni(C(16)H(13)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by two O atoms and one N atom derived from the dianionic N′-[(1E)-1-(5-chloro-2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide ligand and one N atom from the imidazole molecule. The N(2)O(2) donor set defines an approximate square-planar geometry. The dihedral angles between the imidazole ring and the fused six-membered and methoxybenzene rings are 17.78 (14) and 13.23 (16)°, respectively; the dihedral angle between the C(6) rings is 6.63 (12)°. The most prominent feature of the molecular packing is the formation of 4(1)-helical chains (along the c axis) mediated by imidazole-N—H⋯O(phenoxide) hydrogen bonding; these are linked by methyl-C—H⋯Cl interactions. [Image: see text] International Union of Crystallography 2022-03-22 /pmc/articles/PMC9462012/ /pubmed/36339807 http://dx.doi.org/10.1107/S2414314622002954 Text en © Jian-Guo Chang 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Chang, Jian-Guo {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3) O,N′,O′}(1H-imidazole-κN (3))nickel(II) |
title | {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3)
O,N′,O′}(1H-imidazole-κN
(3))nickel(II) |
title_full | {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3)
O,N′,O′}(1H-imidazole-κN
(3))nickel(II) |
title_fullStr | {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3)
O,N′,O′}(1H-imidazole-κN
(3))nickel(II) |
title_full_unstemmed | {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3)
O,N′,O′}(1H-imidazole-κN
(3))nickel(II) |
title_short | {N′-[(E)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3)
O,N′,O′}(1H-imidazole-κN
(3))nickel(II) |
title_sort | {n′-[(e)-1-(5-chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-κ(3)
o,n′,o′}(1h-imidazole-κn
(3))nickel(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462012/ https://www.ncbi.nlm.nih.gov/pubmed/36339807 http://dx.doi.org/10.1107/S2414314622002954 |
work_keys_str_mv | AT changjianguo ne15chloro2oxidophenylethylidene4methoxybenzohydrazidatok3ono1himidazolekn3nickelii |