Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate

The title hybrid compound, (C(5)H(5)N(2)Cl(2))(2)[SnCl(6)]·2H(2)O, was synthesized and its structure was identified by single-crystal X-ray diffraction. The structure is non-polymeric (0D) in terms of containing isolated [SnCl(6)](2−) polyhedra. The special position (0,0,0) of the Sn(IV) atom in the...

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Autores principales: Ghallab, Rochdi, Bougueria, Hassiba, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462013/
https://www.ncbi.nlm.nih.gov/pubmed/36339801
http://dx.doi.org/10.1107/S2414314622001912
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author Ghallab, Rochdi
Bougueria, Hassiba
Merazig, Hocine
author_facet Ghallab, Rochdi
Bougueria, Hassiba
Merazig, Hocine
author_sort Ghallab, Rochdi
collection PubMed
description The title hybrid compound, (C(5)H(5)N(2)Cl(2))(2)[SnCl(6)]·2H(2)O, was synthesized and its structure was identified by single-crystal X-ray diffraction. The structure is non-polymeric (0D) in terms of containing isolated [SnCl(6)](2−) polyhedra. The special position (0,0,0) of the Sn(IV) atom in the crystal structure gives rise to a stacking structure with alternating cationic and anionic layers parallel to (001). The water mol­ecules are inter­calated between these layers, which are linked by cation–anion hydrogen bonds and dominant non-covalent inter­actions. The stability of the three-dimensional network for this compound is also discussed. [Image: see text]
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spelling pubmed-94620132022-11-04 Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate Ghallab, Rochdi Bougueria, Hassiba Merazig, Hocine IUCrdata Data Reports The title hybrid compound, (C(5)H(5)N(2)Cl(2))(2)[SnCl(6)]·2H(2)O, was synthesized and its structure was identified by single-crystal X-ray diffraction. The structure is non-polymeric (0D) in terms of containing isolated [SnCl(6)](2−) polyhedra. The special position (0,0,0) of the Sn(IV) atom in the crystal structure gives rise to a stacking structure with alternating cationic and anionic layers parallel to (001). The water mol­ecules are inter­calated between these layers, which are linked by cation–anion hydrogen bonds and dominant non-covalent inter­actions. The stability of the three-dimensional network for this compound is also discussed. [Image: see text] International Union of Crystallography 2022-03-03 /pmc/articles/PMC9462013/ /pubmed/36339801 http://dx.doi.org/10.1107/S2414314622001912 Text en © Ghallab et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ghallab, Rochdi
Bougueria, Hassiba
Merazig, Hocine
Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate
title Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate
title_full Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate
title_fullStr Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate
title_full_unstemmed Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate
title_short Bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(IV) dihydrate
title_sort bis(2-amino-3,5-di­chloro­pyridinium) hexa­chlorido­stannate(iv) dihydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462013/
https://www.ncbi.nlm.nih.gov/pubmed/36339801
http://dx.doi.org/10.1107/S2414314622001912
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AT merazighocine bis2amino35dichloropyridiniumhexachloridostannateivdihydrate

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