1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate

Crystals of the title compound, C(17)H(15)N(2) (+)·BF(4) (−), were unexpectedly grown from crystallization attempts of [Pt(4,4′-bpy)(4)](BF(4))(2) [Smith et al. (2019 ▸). Comments Inorg. Chem. 39, 188–215] using toluene and aceto­nitrile. The tetra­fluoro­borate anion and the central pyridinium ring...

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Detalles Bibliográficos
Autores principales: Welton, Claire E., Nesterov, Vladimir N., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462016/
https://www.ncbi.nlm.nih.gov/pubmed/36339800
http://dx.doi.org/10.1107/S2414314622002486
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author Welton, Claire E.
Nesterov, Vladimir N.
Smucker, Bradley W.
author_facet Welton, Claire E.
Nesterov, Vladimir N.
Smucker, Bradley W.
author_sort Welton, Claire E.
collection PubMed
description Crystals of the title compound, C(17)H(15)N(2) (+)·BF(4) (−), were unexpectedly grown from crystallization attempts of [Pt(4,4′-bpy)(4)](BF(4))(2) [Smith et al. (2019 ▸). Comments Inorg. Chem. 39, 188–215] using toluene and aceto­nitrile. The tetra­fluoro­borate anion and the central pyridinium ring of the cation are disordered, with atomic site occupancies close to ½. The tolyl group of the cation has a 75.31 (11)° twist relative to the unsubstituted pyridyl group. This rotation allows for a centrosymmetric dimer of cations with weak hydrogen bonding between the pyridyl nitro­gen atom and a methyl H atom on the neighbouring cation. [Image: see text]
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spelling pubmed-94620162022-11-04 1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate Welton, Claire E. Nesterov, Vladimir N. Smucker, Bradley W. IUCrdata Data Reports Crystals of the title compound, C(17)H(15)N(2) (+)·BF(4) (−), were unexpectedly grown from crystallization attempts of [Pt(4,4′-bpy)(4)](BF(4))(2) [Smith et al. (2019 ▸). Comments Inorg. Chem. 39, 188–215] using toluene and aceto­nitrile. The tetra­fluoro­borate anion and the central pyridinium ring of the cation are disordered, with atomic site occupancies close to ½. The tolyl group of the cation has a 75.31 (11)° twist relative to the unsubstituted pyridyl group. This rotation allows for a centrosymmetric dimer of cations with weak hydrogen bonding between the pyridyl nitro­gen atom and a methyl H atom on the neighbouring cation. [Image: see text] International Union of Crystallography 2022-03-10 /pmc/articles/PMC9462016/ /pubmed/36339800 http://dx.doi.org/10.1107/S2414314622002486 Text en © Welton et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Welton, Claire E.
Nesterov, Vladimir N.
Smucker, Bradley W.
1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
title 1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
title_full 1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
title_fullStr 1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
title_full_unstemmed 1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
title_short 1-(2-Methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
title_sort 1-(2-methyl­phen­yl)-4,4′-bipyridin-1-ium tetra­fluorido­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462016/
https://www.ncbi.nlm.nih.gov/pubmed/36339800
http://dx.doi.org/10.1107/S2414314622002486
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