Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3) O:O:O′]bis­[μ(2)-2-(pyridin-3-yl)acetato-κ(2) O:O′]bis­[chlorido­(1,10-phenanthroline-κ(2) N,N′)dysprosium(III)]

The title Dy(III) complex, [Dy(2)(C(7)H(6)NO(2))(4)Cl(2)(C(12)H(8)N(2))(2)] or [Dy(2)(μ (3)-PAA)(4)(Cl)(2)(phen)(2)] (PAA = 3-pyridyl­acetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO(4))(3), 3-pyridyl­acetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Ad...

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Detalles Bibliográficos
Autores principales: Lin, Yan, Yu, Jian-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462020/
https://www.ncbi.nlm.nih.gov/pubmed/36339809
http://dx.doi.org/10.1107/S2414314622002310
Descripción
Sumario:The title Dy(III) complex, [Dy(2)(C(7)H(6)NO(2))(4)Cl(2)(C(12)H(8)N(2))(2)] or [Dy(2)(μ (3)-PAA)(4)(Cl)(2)(phen)(2)] (PAA = 3-pyridyl­acetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO(4))(3), 3-pyridyl­acetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected via face-to-face π–π stacking inter­actions resulting in supra­molecular chains along the c-axis direction. [Image: see text]

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