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Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3) O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2) O:O′]bis[chlorido(1,10-phenanthroline-κ(2) N,N′)dysprosium(III)]
The title Dy(III) complex, [Dy(2)(C(7)H(6)NO(2))(4)Cl(2)(C(12)H(8)N(2))(2)] or [Dy(2)(μ (3)-PAA)(4)(Cl)(2)(phen)(2)] (PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO(4))(3), 3-pyridylacetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Ad...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462020/ https://www.ncbi.nlm.nih.gov/pubmed/36339809 http://dx.doi.org/10.1107/S2414314622002310 |
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author | Lin, Yan Yu, Jian-Ping |
author_facet | Lin, Yan Yu, Jian-Ping |
author_sort | Lin, Yan |
collection | PubMed |
description | The title Dy(III) complex, [Dy(2)(C(7)H(6)NO(2))(4)Cl(2)(C(12)H(8)N(2))(2)] or [Dy(2)(μ (3)-PAA)(4)(Cl)(2)(phen)(2)] (PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO(4))(3), 3-pyridylacetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected via face-to-face π–π stacking interactions resulting in supramolecular chains along the c-axis direction. [Image: see text] |
format | Online Article Text |
id | pubmed-9462020 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94620202022-11-04 Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3) O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2) O:O′]bis[chlorido(1,10-phenanthroline-κ(2) N,N′)dysprosium(III)] Lin, Yan Yu, Jian-Ping IUCrdata Data Reports The title Dy(III) complex, [Dy(2)(C(7)H(6)NO(2))(4)Cl(2)(C(12)H(8)N(2))(2)] or [Dy(2)(μ (3)-PAA)(4)(Cl)(2)(phen)(2)] (PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO(4))(3), 3-pyridylacetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected via face-to-face π–π stacking interactions resulting in supramolecular chains along the c-axis direction. [Image: see text] International Union of Crystallography 2022-03-31 /pmc/articles/PMC9462020/ /pubmed/36339809 http://dx.doi.org/10.1107/S2414314622002310 Text en © Lin and Yu 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Lin, Yan Yu, Jian-Ping Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3) O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2) O:O′]bis[chlorido(1,10-phenanthroline-κ(2) N,N′)dysprosium(III)] |
title | Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3)
O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2)
O:O′]bis[chlorido(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III)] |
title_full | Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3)
O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2)
O:O′]bis[chlorido(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III)] |
title_fullStr | Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3)
O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2)
O:O′]bis[chlorido(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III)] |
title_full_unstemmed | Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3)
O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2)
O:O′]bis[chlorido(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III)] |
title_short | Bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3)
O:O:O′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2)
O:O′]bis[chlorido(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III)] |
title_sort | bis[μ(3)-2-(pyridin-3-yl)acetato-κ(3)
o:o:o′]bis[μ(2)-2-(pyridin-3-yl)acetato-κ(2)
o:o′]bis[chlorido(1,10-phenanthroline-κ(2)
n,n′)dysprosium(iii)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462020/ https://www.ncbi.nlm.nih.gov/pubmed/36339809 http://dx.doi.org/10.1107/S2414314622002310 |
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