4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene

In the title compound, C(32)H(29)BrN(2)O(10)S(3), the benzo­thia­zole and thio­phene ring systems subtend an inter­planar angle of 7.43 (12)°. The NH(2) group forms intra­molecular hydrogen bonds to N(thia­zole) and O(carbon­yl). The S(galactose)—C(thio­phene) bond is short [1.759 (2) Å]. The mol­ec...

Descripción completa

Detalles Bibliográficos
Autores principales: Azzam, Rasha A., Elgemeie, Galal H., Gad, Nagwa M., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462023/
https://www.ncbi.nlm.nih.gov/pubmed/36337688
http://dx.doi.org/10.1107/S2414314622004126
_version_ 1784787085091143680
author Azzam, Rasha A.
Elgemeie, Galal H.
Gad, Nagwa M.
Jones, Peter G.
author_facet Azzam, Rasha A.
Elgemeie, Galal H.
Gad, Nagwa M.
Jones, Peter G.
author_sort Azzam, Rasha A.
collection PubMed
description In the title compound, C(32)H(29)BrN(2)O(10)S(3), the benzo­thia­zole and thio­phene ring systems subtend an inter­planar angle of 7.43 (12)°. The NH(2) group forms intra­molecular hydrogen bonds to N(thia­zole) and O(carbon­yl). The S(galactose)—C(thio­phene) bond is short [1.759 (2) Å]. The mol­ecules are connected to form ribbons parallel to the b axis by two ‘weak’ hydrogen bonds and a short N(amino)⋯S(galactose) contact. [Image: see text]
format Online
Article
Text
id pubmed-9462023
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94620232022-11-04 4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene Azzam, Rasha A. Elgemeie, Galal H. Gad, Nagwa M. Jones, Peter G. IUCrdata Data Reports In the title compound, C(32)H(29)BrN(2)O(10)S(3), the benzo­thia­zole and thio­phene ring systems subtend an inter­planar angle of 7.43 (12)°. The NH(2) group forms intra­molecular hydrogen bonds to N(thia­zole) and O(carbon­yl). The S(galactose)—C(thio­phene) bond is short [1.759 (2) Å]. The mol­ecules are connected to form ribbons parallel to the b axis by two ‘weak’ hydrogen bonds and a short N(amino)⋯S(galactose) contact. [Image: see text] International Union of Crystallography 2022-04-28 /pmc/articles/PMC9462023/ /pubmed/36337688 http://dx.doi.org/10.1107/S2414314622004126 Text en © Azzam et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Azzam, Rasha A.
Elgemeie, Galal H.
Gad, Nagwa M.
Jones, Peter G.
4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
title 4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
title_full 4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
title_fullStr 4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
title_full_unstemmed 4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
title_short 4-Amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-O-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
title_sort 4-amino-5-(4-bromo­benzo­yl)-3-(benzo[d]thia­zol-2-yl)-2-[(2′,3′,4′,6′-tetra-o-acetyl-β-d-galacto­pyran­osyl­)sulfanyl]­thio­phene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462023/
https://www.ncbi.nlm.nih.gov/pubmed/36337688
http://dx.doi.org/10.1107/S2414314622004126
work_keys_str_mv AT azzamrashaa 4amino54bromobenzoyl3benzodthiazol2yl22346tetraoacetylbdgalactopyranosylsulfanylthiophene
AT elgemeiegalalh 4amino54bromobenzoyl3benzodthiazol2yl22346tetraoacetylbdgalactopyranosylsulfanylthiophene
AT gadnagwam 4amino54bromobenzoyl3benzodthiazol2yl22346tetraoacetylbdgalactopyranosylsulfanylthiophene
AT jonespeterg 4amino54bromobenzoyl3benzodthiazol2yl22346tetraoacetylbdgalactopyranosylsulfanylthiophene

Ejemplares similares