1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide

The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the mol­ecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable inter­molecular distance for π–π inter­actions. These cationic columns are further stabilized by inte...

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Detalles Bibliográficos
Autores principales: Schuster, Sara A., Nesterov, Volodymyr V., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462032/
https://www.ncbi.nlm.nih.gov/pubmed/36338934
http://dx.doi.org/10.1107/S2414314622005260
Descripción
Sumario:The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the mol­ecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable inter­molecular distance for π–π inter­actions. These cationic columns are further stabilized by inter­columnar C—H⋯N hydrogen bonding with the bromide ions distributed between them. [Image: see text]

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