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1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide
The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the molecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable intermolecular distance for π–π interactions. These cationic columns are further stabilized by inte...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462032/ https://www.ncbi.nlm.nih.gov/pubmed/36338934 http://dx.doi.org/10.1107/S2414314622005260 |
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author | Schuster, Sara A. Nesterov, Volodymyr V. Smucker, Bradley W. |
author_facet | Schuster, Sara A. Nesterov, Volodymyr V. Smucker, Bradley W. |
author_sort | Schuster, Sara A. |
collection | PubMed |
description | The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the molecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable intermolecular distance for π–π interactions. These cationic columns are further stabilized by intercolumnar C—H⋯N hydrogen bonding with the bromide ions distributed between them. [Image: see text] |
format | Online Article Text |
id | pubmed-9462032 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94620322022-11-04 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide Schuster, Sara A. Nesterov, Volodymyr V. Smucker, Bradley W. IUCrdata Data Reports The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the molecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable intermolecular distance for π–π interactions. These cationic columns are further stabilized by intercolumnar C—H⋯N hydrogen bonding with the bromide ions distributed between them. [Image: see text] International Union of Crystallography 2022-05-20 /pmc/articles/PMC9462032/ /pubmed/36338934 http://dx.doi.org/10.1107/S2414314622005260 Text en © Schuster et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Schuster, Sara A. Nesterov, Volodymyr V. Smucker, Bradley W. 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide |
title | 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide |
title_full | 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide |
title_fullStr | 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide |
title_full_unstemmed | 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide |
title_short | 1,1′-Methylenebis(4,4′-bipyridin-1-ium) dibromide |
title_sort | 1,1′-methylenebis(4,4′-bipyridin-1-ium) dibromide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462032/ https://www.ncbi.nlm.nih.gov/pubmed/36338934 http://dx.doi.org/10.1107/S2414314622005260 |
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