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1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide

The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the mol­ecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable inter­molecular distance for π–π inter­actions. These cationic columns are further stabilized by inte...

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Detalles Bibliográficos
Autores principales: Schuster, Sara A., Nesterov, Volodymyr V., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462032/
https://www.ncbi.nlm.nih.gov/pubmed/36338934
http://dx.doi.org/10.1107/S2414314622005260
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author Schuster, Sara A.
Nesterov, Volodymyr V.
Smucker, Bradley W.
author_facet Schuster, Sara A.
Nesterov, Volodymyr V.
Smucker, Bradley W.
author_sort Schuster, Sara A.
collection PubMed
description The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the mol­ecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable inter­molecular distance for π–π inter­actions. These cationic columns are further stabilized by inter­columnar C—H⋯N hydrogen bonding with the bromide ions distributed between them. [Image: see text]
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spelling pubmed-94620322022-11-04 1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide Schuster, Sara A. Nesterov, Volodymyr V. Smucker, Bradley W. IUCrdata Data Reports The asymmetric unit of the title salt, C(21)H(18)N(4) (2+)·2Br(−), comprises half of the mol­ecule and a bromide ion. The chevron-shaped cations stack as columns in the [001] direction with suitable inter­molecular distance for π–π inter­actions. These cationic columns are further stabilized by inter­columnar C—H⋯N hydrogen bonding with the bromide ions distributed between them. [Image: see text] International Union of Crystallography 2022-05-20 /pmc/articles/PMC9462032/ /pubmed/36338934 http://dx.doi.org/10.1107/S2414314622005260 Text en © Schuster et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schuster, Sara A.
Nesterov, Volodymyr V.
Smucker, Bradley W.
1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide
title 1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide
title_full 1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide
title_fullStr 1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide
title_full_unstemmed 1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide
title_short 1,1′-Methyl­enebis(4,4′-bipyridin-1-ium) dibromide
title_sort 1,1′-methyl­enebis(4,4′-bipyridin-1-ium) dibromide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462032/
https://www.ncbi.nlm.nih.gov/pubmed/36338934
http://dx.doi.org/10.1107/S2414314622005260
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