Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate

The title compound, [Nb(6)Cl(12)I(2)(H(2)O)(4)]·8THF (THF is tetra­hydro­furan, C(4)H(8)O), comprises an uncharged niobium cluster unit surrounded by THF solvent mol­ecules. The edges of the {Nb(6)} octa­hedron are μ (2)-coordinated by twelve chlorido ligands. Four in-plane (equatorial plane) aqua l...

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Detalles Bibliográficos
Autores principales: Schröder, Florian, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462034/
https://www.ncbi.nlm.nih.gov/pubmed/36339892
http://dx.doi.org/10.1107/S2414314622006186
Descripción
Sumario:The title compound, [Nb(6)Cl(12)I(2)(H(2)O)(4)]·8THF (THF is tetra­hydro­furan, C(4)H(8)O), comprises an uncharged niobium cluster unit surrounded by THF solvent mol­ecules. The edges of the {Nb(6)} octa­hedron are μ (2)-coordinated by twelve chlorido ligands. Four in-plane (equatorial plane) aqua ligands and two iodido ligands coordinating above and below the plane are bound at the corners of the {Nb(6)} atomic octa­hedron. O—H⋯O hydrogen bonds are formed between the aqua ligands and the THF solvent mol­ecules; one THF molecule is disordered over two positions with the major component having a site occupancy of 0.64 (2). [Image: see text]

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