Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate

The title compound, [Nb(6)Cl(12)I(2)(H(2)O)(4)]·8THF (THF is tetra­hydro­furan, C(4)H(8)O), comprises an uncharged niobium cluster unit surrounded by THF solvent mol­ecules. The edges of the {Nb(6)} octa­hedron are μ (2)-coordinated by twelve chlorido ligands. Four in-plane (equatorial plane) aqua l...

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Detalles Bibliográficos
Autores principales: Schröder, Florian, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462034/
https://www.ncbi.nlm.nih.gov/pubmed/36339892
http://dx.doi.org/10.1107/S2414314622006186
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author Schröder, Florian
Köckerling, Martin
author_facet Schröder, Florian
Köckerling, Martin
author_sort Schröder, Florian
collection PubMed
description The title compound, [Nb(6)Cl(12)I(2)(H(2)O)(4)]·8THF (THF is tetra­hydro­furan, C(4)H(8)O), comprises an uncharged niobium cluster unit surrounded by THF solvent mol­ecules. The edges of the {Nb(6)} octa­hedron are μ (2)-coordinated by twelve chlorido ligands. Four in-plane (equatorial plane) aqua ligands and two iodido ligands coordinating above and below the plane are bound at the corners of the {Nb(6)} atomic octa­hedron. O—H⋯O hydrogen bonds are formed between the aqua ligands and the THF solvent mol­ecules; one THF molecule is disordered over two positions with the major component having a site occupancy of 0.64 (2). [Image: see text]
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spelling pubmed-94620342022-11-04 Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate Schröder, Florian Köckerling, Martin IUCrdata Data Reports The title compound, [Nb(6)Cl(12)I(2)(H(2)O)(4)]·8THF (THF is tetra­hydro­furan, C(4)H(8)O), comprises an uncharged niobium cluster unit surrounded by THF solvent mol­ecules. The edges of the {Nb(6)} octa­hedron are μ (2)-coordinated by twelve chlorido ligands. Four in-plane (equatorial plane) aqua ligands and two iodido ligands coordinating above and below the plane are bound at the corners of the {Nb(6)} atomic octa­hedron. O—H⋯O hydrogen bonds are formed between the aqua ligands and the THF solvent mol­ecules; one THF molecule is disordered over two positions with the major component having a site occupancy of 0.64 (2). [Image: see text] International Union of Crystallography 2022-06-16 /pmc/articles/PMC9462034/ /pubmed/36339892 http://dx.doi.org/10.1107/S2414314622006186 Text en © Schröder and Köckerling 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schröder, Florian
Köckerling, Martin
Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate
title Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate
title_full Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate
title_fullStr Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate
title_full_unstemmed Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate
title_short Tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 Nb—Nb) tetra­hydro­furan octa­solvate
title_sort tetra­aqua­dodekakis-μ(2)-chlorido-di­iodido-octa­hedro-hexa­niobium(12 nb—nb) tetra­hydro­furan octa­solvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462034/
https://www.ncbi.nlm.nih.gov/pubmed/36339892
http://dx.doi.org/10.1107/S2414314622006186
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AT kockerlingmartin tetraaquadodekakism2chloridodiiodidooctahedrohexaniobium12nbnbtetrahydrofuranoctasolvate

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