trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate

The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetra­fluoro­ethyl­ene complex that had been anti­cipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))...

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Detalles Bibliográficos
Autor principal: Corfield, Peter W. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/
https://www.ncbi.nlm.nih.gov/pubmed/36339894
http://dx.doi.org/10.1107/S2414314622006071
Descripción
Sumario:The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetra­fluoro­ethyl­ene complex that had been anti­cipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))(3))(2) with C(2)F(4) in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF(4) (−) anions are linked by C—H⋯F and C—H⋯O inter­actions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967. [Image: see text]

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