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trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate
The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/ https://www.ncbi.nlm.nih.gov/pubmed/36339894 http://dx.doi.org/10.1107/S2414314622006071 |
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author | Corfield, Peter W. R. |
author_facet | Corfield, Peter W. R. |
author_sort | Corfield, Peter W. R. |
collection | PubMed |
description | The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))(3))(2) with C(2)F(4) in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF(4) (−) anions are linked by C—H⋯F and C—H⋯O interactions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967. [Image: see text] |
format | Online Article Text |
id | pubmed-9462037 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94620372022-11-04 trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate Corfield, Peter W. R. IUCrdata Data Reports The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))(3))(2) with C(2)F(4) in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF(4) (−) anions are linked by C—H⋯F and C—H⋯O interactions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967. [Image: see text] International Union of Crystallography 2022-06-10 /pmc/articles/PMC9462037/ /pubmed/36339894 http://dx.doi.org/10.1107/S2414314622006071 Text en © Peter W. R. Corfield 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Corfield, Peter W. R. trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate |
title |
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate |
title_full |
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate |
title_fullStr |
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate |
title_full_unstemmed |
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate |
title_short |
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate |
title_sort | trans-carbonylchloridobis(triethylphosphane-κp)platinum(ii) tetrafluoridoborate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/ https://www.ncbi.nlm.nih.gov/pubmed/36339894 http://dx.doi.org/10.1107/S2414314622006071 |
work_keys_str_mv | AT corfieldpeterwr transcarbonylchloridobistriethylphosphanekpplatinumiitetrafluoridoborate |