trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate

The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetra­fluoro­ethyl­ene complex that had been anti­cipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))...

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Detalles Bibliográficos
Autor principal: Corfield, Peter W. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/
https://www.ncbi.nlm.nih.gov/pubmed/36339894
http://dx.doi.org/10.1107/S2414314622006071
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author Corfield, Peter W. R.
author_facet Corfield, Peter W. R.
author_sort Corfield, Peter W. R.
collection PubMed
description The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetra­fluoro­ethyl­ene complex that had been anti­cipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))(3))(2) with C(2)F(4) in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF(4) (−) anions are linked by C—H⋯F and C—H⋯O inter­actions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967. [Image: see text]
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spelling pubmed-94620372022-11-04 trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate Corfield, Peter W. R. IUCrdata Data Reports The chemical formulation of the title compound was established as trans-[PtCl{P(C(2)H(5))(3)(CO)}BF(4) by single-crystal X-ray analysis, in contrast to the five-coordinate tetra­fluoro­ethyl­ene complex that had been anti­cipated. The compound had been prepared by reaction of trans-PtHCl(P(C(2)H(5))(3))(2) with C(2)F(4) in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF(4) (−) anions are linked by C—H⋯F and C—H⋯O inter­actions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967. [Image: see text] International Union of Crystallography 2022-06-10 /pmc/articles/PMC9462037/ /pubmed/36339894 http://dx.doi.org/10.1107/S2414314622006071 Text en © Peter W. R. Corfield 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Corfield, Peter W. R.
trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate
title trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate
title_full trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate
title_fullStr trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate
title_full_unstemmed trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate
title_short trans-Carbonyl­chlorido­bis­(tri­ethyl­phosphane-κP)platinum(II) tetra­fluorido­borate
title_sort trans-carbonyl­chlorido­bis­(tri­ethyl­phosphane-κp)platinum(ii) tetra­fluorido­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/
https://www.ncbi.nlm.nih.gov/pubmed/36339894
http://dx.doi.org/10.1107/S2414314622006071
work_keys_str_mv AT corfieldpeterwr transcarbonylchloridobistriethylphosphanekpplatinumiitetrafluoridoborate

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