Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth

The title compound, [Bi(C(9)H(6)NS(2))(3)], was prepared by reacting BiCl(3) and 2-mercapto-4-phenyl­thia­zole (LH) at room temperature in a stoichiometric ratio of 1:4. The mol­ecular structure reveals a slightly distorted square-pyramidal environment around the Bi(III) atom. Two of the three monoa...

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Detalles Bibliográficos
Autores principales: Stammler, Hans-Georg, Imran, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462144/
https://www.ncbi.nlm.nih.gov/pubmed/36337719
http://dx.doi.org/10.1107/S241431462000067X
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author Stammler, Hans-Georg
Imran, Muhammad
author_facet Stammler, Hans-Georg
Imran, Muhammad
author_sort Stammler, Hans-Georg
collection PubMed
description The title compound, [Bi(C(9)H(6)NS(2))(3)], was prepared by reacting BiCl(3) and 2-mercapto-4-phenyl­thia­zole (LH) at room temperature in a stoichiometric ratio of 1:4. The mol­ecular structure reveals a slightly distorted square-pyramidal environment around the Bi(III) atom. Two of the three monoanionic ligands L (−) coordinate in an N,S-bidentate mode, while one shows a monodentate mode through an S atom. There are no significant inter­molecular inter­actions present in the crystal. [Image: see text]
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spelling pubmed-94621442022-11-04 Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth Stammler, Hans-Georg Imran, Muhammad IUCrdata Data Reports The title compound, [Bi(C(9)H(6)NS(2))(3)], was prepared by reacting BiCl(3) and 2-mercapto-4-phenyl­thia­zole (LH) at room temperature in a stoichiometric ratio of 1:4. The mol­ecular structure reveals a slightly distorted square-pyramidal environment around the Bi(III) atom. Two of the three monoanionic ligands L (−) coordinate in an N,S-bidentate mode, while one shows a monodentate mode through an S atom. There are no significant inter­molecular inter­actions present in the crystal. [Image: see text] International Union of Crystallography 2020-01-28 /pmc/articles/PMC9462144/ /pubmed/36337719 http://dx.doi.org/10.1107/S241431462000067X Text en © Stammler and Imran 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Stammler, Hans-Georg
Imran, Muhammad
Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth
title Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth
title_full Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth
title_fullStr Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth
title_full_unstemmed Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth
title_short Bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) S (2),N)(4-phenyl-1,3-thia­zole-2-thiol­ato-κS (2))bis­muth
title_sort bis(4-phenyl-2-sulfanyl­idene-2,3-di­hydro-1,3-thia­zol-3-ido-κ(2) s (2),n)(4-phenyl-1,3-thia­zole-2-thiol­ato-κs (2))bis­muth
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462144/
https://www.ncbi.nlm.nih.gov/pubmed/36337719
http://dx.doi.org/10.1107/S241431462000067X
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