Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)

The title compound, [Co(C(18)H(37)N(2))(2)(NCS)(4)], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane (DABCO(+)) cations, which carry n-dodecyl chains at the non-coo...

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Detalles Bibliográficos
Autores principales: Giltzau, Niels Ole, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462146/
https://www.ncbi.nlm.nih.gov/pubmed/36337714
http://dx.doi.org/10.1107/S2414314620000231
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author Giltzau, Niels Ole
Köckerling, Martin
author_facet Giltzau, Niels Ole
Köckerling, Martin
author_sort Giltzau, Niels Ole
collection PubMed
description The title compound, [Co(C(18)H(37)N(2))(2)(NCS)(4)], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane (DABCO(+)) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octa­hedral coordination environment of the Co(II) ion is completed through four N atoms of iso­thio­cyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C—H⋯N and C—H⋯S between the filamentous mol­ecules lead to the formation of layers parallel to (001). [Image: see text]
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spelling pubmed-94621462022-11-04 Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II) Giltzau, Niels Ole Köckerling, Martin IUCrdata Data Reports The title compound, [Co(C(18)H(37)N(2))(2)(NCS)(4)], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane (DABCO(+)) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octa­hedral coordination environment of the Co(II) ion is completed through four N atoms of iso­thio­cyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C—H⋯N and C—H⋯S between the filamentous mol­ecules lead to the formation of layers parallel to (001). [Image: see text] International Union of Crystallography 2020-01-28 /pmc/articles/PMC9462146/ /pubmed/36337714 http://dx.doi.org/10.1107/S2414314620000231 Text en © Giltzau and Köckerling 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Giltzau, Niels Ole
Köckerling, Martin
Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)
title Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)
title_full Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)
title_fullStr Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)
title_full_unstemmed Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)
title_short Bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(II)
title_sort bis(1-dodecyl-4-aza-1-azoniabi­cyclo­[2.2.2]octane)tetra­iso­thio­cyanato­cobalt(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462146/
https://www.ncbi.nlm.nih.gov/pubmed/36337714
http://dx.doi.org/10.1107/S2414314620000231
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