2H-[1,3]Thia­zolo[5,4,3-ij]quinolin-3-ium chloride monohydrate

The structure of the title hydrated mol­ecular salt, C(10)H(8)NS(+)·Cl(−)·H(2)O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH(2)Cl(2) and an aqueous solution of [Bu(4)N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features cha...

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Detalles Bibliográficos
Autores principales: Ehweiner, Madeleine A., Belaj, Ferdinand, Mösch-Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462152/
https://www.ncbi.nlm.nih.gov/pubmed/36340016
http://dx.doi.org/10.1107/S2414314620014650
Descripción
Sumario:The structure of the title hydrated mol­ecular salt, C(10)H(8)NS(+)·Cl(−)·H(2)O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH(2)Cl(2) and an aqueous solution of [Bu(4)N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features chains built by alternating Cl(−) anions and H(2)O mol­ecules connected by O—H⋯O hydrogen bonds. The cation shows whole-mol­ecule disorder over two flipped orientations in a 0.853 (3):0.147 (3) ratio. [Image: see text]

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