(3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane

The title compound, C(8)H(16)N(2)Si, crystallizes in the the ortho­rhom­bic space group P2(1)2(1)2(1) with one mol­ecule in the asymmetric unit. The Si—N bond is 1.782 (2) Å, which is substanti­ally longer than is found in comparable (3,5-di­methyl­pyrazol­yl)silanes. The tri­methyl­silyl group adop...

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Detalles Bibliográficos
Autores principales: Böhme, Uwe, Bitto, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462153/
https://www.ncbi.nlm.nih.gov/pubmed/36340014
http://dx.doi.org/10.1107/S2414314620014443
Descripción
Sumario:The title compound, C(8)H(16)N(2)Si, crystallizes in the the ortho­rhom­bic space group P2(1)2(1)2(1) with one mol­ecule in the asymmetric unit. The Si—N bond is 1.782 (2) Å, which is substanti­ally longer than is found in comparable (3,5-di­methyl­pyrazol­yl)silanes. The tri­methyl­silyl group adopts a staggered conformation with respect to the planar 3,5-di­methyl­pyrazolyl unit. C—H⋯N hydrogen bonds between neighboring mol­ecules form a strand of mol­ecules along the b-axis direction. [Image: see text]

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