(3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane

The title compound, C(8)H(16)N(2)Si, crystallizes in the the ortho­rhom­bic space group P2(1)2(1)2(1) with one mol­ecule in the asymmetric unit. The Si—N bond is 1.782 (2) Å, which is substanti­ally longer than is found in comparable (3,5-di­methyl­pyrazol­yl)silanes. The tri­methyl­silyl group adop...

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Detalles Bibliográficos
Autores principales: Böhme, Uwe, Bitto, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462153/
https://www.ncbi.nlm.nih.gov/pubmed/36340014
http://dx.doi.org/10.1107/S2414314620014443
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author Böhme, Uwe
Bitto, Florian
author_facet Böhme, Uwe
Bitto, Florian
author_sort Böhme, Uwe
collection PubMed
description The title compound, C(8)H(16)N(2)Si, crystallizes in the the ortho­rhom­bic space group P2(1)2(1)2(1) with one mol­ecule in the asymmetric unit. The Si—N bond is 1.782 (2) Å, which is substanti­ally longer than is found in comparable (3,5-di­methyl­pyrazol­yl)silanes. The tri­methyl­silyl group adopts a staggered conformation with respect to the planar 3,5-di­methyl­pyrazolyl unit. C—H⋯N hydrogen bonds between neighboring mol­ecules form a strand of mol­ecules along the b-axis direction. [Image: see text]
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spelling pubmed-94621532022-11-04 (3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane Böhme, Uwe Bitto, Florian IUCrdata Data Reports The title compound, C(8)H(16)N(2)Si, crystallizes in the the ortho­rhom­bic space group P2(1)2(1)2(1) with one mol­ecule in the asymmetric unit. The Si—N bond is 1.782 (2) Å, which is substanti­ally longer than is found in comparable (3,5-di­methyl­pyrazol­yl)silanes. The tri­methyl­silyl group adopts a staggered conformation with respect to the planar 3,5-di­methyl­pyrazolyl unit. C—H⋯N hydrogen bonds between neighboring mol­ecules form a strand of mol­ecules along the b-axis direction. [Image: see text] International Union of Crystallography 2020-11-06 /pmc/articles/PMC9462153/ /pubmed/36340014 http://dx.doi.org/10.1107/S2414314620014443 Text en © Böhme and Bitto 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Böhme, Uwe
Bitto, Florian
(3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane
title (3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane
title_full (3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane
title_fullStr (3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane
title_full_unstemmed (3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane
title_short (3,5-Dimethyl-1H-pyrazol-1-yl)tri­methyl­silane
title_sort (3,5-dimethyl-1h-pyrazol-1-yl)tri­methyl­silane
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462153/
https://www.ncbi.nlm.nih.gov/pubmed/36340014
http://dx.doi.org/10.1107/S2414314620014443
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